FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3105626814> ?p ?o ?g. }

• W3105626814 endingPage "279" @default.
• W3105626814 startingPage "271" @default.
• W3105626814 abstract "Water as an auxiliary solvent is added to various alcohol solvents (methanol, ethanol, and isopropanol) and N,N-dimethylformamide (DMF) to form a variety of liquid mixtures, which are divided into different types according to different proportions. Starting from pure water, 0.1 mass fraction of organic solvents is added at a time until the ratio of organic solvent is 1. The abovementioned liquid mixtures are used as solvents to dissolve halosulfuron-methyl at 278.15–323.15 K under 101.2 kPa by means of the isothermal static technique. The experimental solubility of halosulfuron-methyl was calculated and validated by using three various computational models, i.e., Jouyban–Acree model, modified Apelblat–Jouyban–Acree model, and van’t Hoff–Jouyban–Acree model. Considering that there are many factors that change the experimental results, this experiment mainly selected temperature and water content as two factors as the main independent variables. From the point of view of temperature, it changes from a low value to a high value, so it is obvious that the solute mole fraction also follows its footsteps. Unlike the temperature, as the organic solvent is continuously diluted by water, the solute solubility changes in the opposite direction to the water content. By controlling the variable method to ensure that the above two variables remain unchanged, DMF has the best dispersion ability for all the selected solvents to dissolve halosulfuron-methyl. The solubility maximum of 2.542 × 10–3 at 323.15 K was found in pure DMF, and four systems followed the descending order as (DMF + water) > (ethanol + water) > (methanol + water) > (isopropanol + water). The largest relative average deviation and root-mean-square deviation values were 5.70 × 10–3 and 6.90 × 10–6, respectively. For drugs with poor water solubility and dissolution rate, measuring their solubility and understanding their dissolution properties could effectively help solve the problem of nonwetting and nondiffusion. The obtained equilibrium solubility and correlation parameters of halosulfuron-methyl in studied cosolvency systems could be favorable for the industrial production, recrystallization, and purification processes of API halosulfuron-methyl." @default.
• W3105626814 created "2020-11-23" @default.
• W3105626814 creator A5027557441 @default.
• W3105626814 creator A5036604570 @default.
• W3105626814 creator A5053984055 @default.
• W3105626814 creator A5058376744 @default.
• W3105626814 creator A5083094349 @default.
• W3105626814 date "2020-11-18" @default.
• W3105626814 modified "2023-09-27" @default.
• W3105626814 title "Equilibrium Solubility Investigation and Thermodynamic Computational Modeling of Halosulfuron-methyl in a Series of Cosolvent Mixtures at a Temperature Range of 278.15–323.15 K" @default.
• W3105626814 cites W1600161348 @default.
• W3105626814 cites W1996774206 @default.
• W3105626814 cites W2001054843 @default.
• W3105626814 cites W2016679297 @default.
• W3105626814 cites W2024100877 @default.
• W3105626814 cites W2035709988 @default.
• W3105626814 cites W2057875667 @default.
• W3105626814 cites W2060482516 @default.
• W3105626814 cites W2072476365 @default.
• W3105626814 cites W2082436969 @default.
• W3105626814 cites W2150559203 @default.
• W3105626814 cites W2204932366 @default.
• W3105626814 cites W2273191926 @default.
• W3105626814 cites W2325844933 @default.
• W3105626814 cites W2387830886 @default.
• W3105626814 cites W2464503441 @default.
• W3105626814 cites W2473163679 @default.
• W3105626814 cites W2529856339 @default.
• W3105626814 cites W2791667619 @default.
• W3105626814 cites W2792353454 @default.
• W3105626814 cites W3005179101 @default.
• W3105626814 cites W3011191448 @default.
• W3105626814 cites W3016446193 @default.
• W3105626814 cites W3038978296 @default.
• W3105626814 cites W4210449401 @default.
• W3105626814 doi "https://doi.org/10.1021/acs.jced.0c00633" @default.
• W3105626814 hasPublicationYear "2020" @default.
• W3105626814 type Work @default.
• W3105626814 sameAs 3105626814 @default.
• W3105626814 citedByCount "3" @default.
• W3105626814 countsByYear W31056268142021 @default.
• W3105626814 countsByYear W31056268142022 @default.
• W3105626814 countsByYear W31056268142023 @default.
• W3105626814 crossrefType "journal-article" @default.
• W3105626814 hasAuthorship W3105626814A5027557441 @default.
• W3105626814 hasAuthorship W3105626814A5036604570 @default.
• W3105626814 hasAuthorship W3105626814A5053984055 @default.
• W3105626814 hasAuthorship W3105626814A5058376744 @default.
• W3105626814 hasAuthorship W3105626814A5083094349 @default.
• W3105626814 hasConcept C116628846 @default.
• W3105626814 hasConcept C121332964 @default.
• W3105626814 hasConcept C133347239 @default.
• W3105626814 hasConcept C147789679 @default.
• W3105626814 hasConcept C155574463 @default.
• W3105626814 hasConcept C178790620 @default.
• W3105626814 hasConcept C185592680 @default.
• W3105626814 hasConcept C2779607525 @default.
• W3105626814 hasConcept C2780471494 @default.
• W3105626814 hasConcept C2781066024 @default.
• W3105626814 hasConcept C36591836 @default.
• W3105626814 hasConcept C97355855 @default.
• W3105626814 hasConceptScore W3105626814C116628846 @default.
• W3105626814 hasConceptScore W3105626814C121332964 @default.
• W3105626814 hasConceptScore W3105626814C133347239 @default.
• W3105626814 hasConceptScore W3105626814C147789679 @default.
• W3105626814 hasConceptScore W3105626814C155574463 @default.
• W3105626814 hasConceptScore W3105626814C178790620 @default.
• W3105626814 hasConceptScore W3105626814C185592680 @default.
• W3105626814 hasConceptScore W3105626814C2779607525 @default.
• W3105626814 hasConceptScore W3105626814C2780471494 @default.
• W3105626814 hasConceptScore W3105626814C2781066024 @default.
• W3105626814 hasConceptScore W3105626814C36591836 @default.
• W3105626814 hasConceptScore W3105626814C97355855 @default.
• W3105626814 hasFunder F4320321001 @default.
• W3105626814 hasIssue "1" @default.
• W3105626814 hasLocation W31056268141 @default.
• W3105626814 hasOpenAccess W3105626814 @default.
• W3105626814 hasPrimaryLocation W31056268141 @default.
• W3105626814 hasRelatedWork W1966595777 @default.
• W3105626814 hasRelatedWork W1979139756 @default.
• W3105626814 hasRelatedWork W2050593174 @default.
• W3105626814 hasRelatedWork W2311958125 @default.
• W3105626814 hasRelatedWork W2917158758 @default.
• W3105626814 hasRelatedWork W2922403229 @default.
• W3105626814 hasRelatedWork W2952639941 @default.
• W3105626814 hasRelatedWork W3043394985 @default.
• W3105626814 hasRelatedWork W4220820285 @default.
• W3105626814 hasRelatedWork W4243817369 @default.
• W3105626814 hasVolume "66" @default.
• W3105626814 isParatext "false" @default.
• W3105626814 isRetracted "false" @default.
• W3105626814 magId "3105626814" @default.
• W3105626814 workType "article" @default.