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- W3106091301 abstract "Abstract Since the discovery of the Verwey transition in magnetite, transition metal compounds with pyrochlore structures have been intensively studied as a platform for realizing remarkable electronic phase transitions. We report on a phase transition that preserves the cubic symmetry of the β-pyrochlore oxide CsW 2 O 6 , where each of W 5 d electrons are confined in regular-triangle W 3 trimers. This trimer formation represents the self-organization of 5 d electrons, which can be resolved into a charge order satisfying the Anderson condition in a nontrivial way, orbital order caused by the distortion of WO 6 octahedra, and the formation of a spin-singlet pair in a regular-triangle trimer. An electronic instability due to the unusual three-dimensional nesting of Fermi surfaces and the strong correlations of the 5 d electrons characteristic of the pyrochlore oxides are both likely to play important roles in this charge-orbital-spin coupled phenomenon." @default.
- W3106091301 created "2020-11-23" @default.
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- W3106091301 date "2020-06-19" @default.
- W3106091301 modified "2023-10-14" @default.
- W3106091301 title "Regular-triangle trimer and charge order preserving the Anderson condition in the pyrochlore structure of CsW2O6" @default.
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- W3106091301 doi "https://doi.org/10.1038/s41467-020-16873-7" @default.
- W3106091301 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7305186" @default.
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