FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3106509803> ?p ?o ?g. }

• W3106509803 endingPage "29656" @default.
• W3106509803 startingPage "29642" @default.
• W3106509803 abstract "Polyaniline (PANI)-wrapped TiO2 nanorods (PANI/TiO2), obtained through the oxidative polymerization of aniline at the surface of hydrothermally presynthesized TiO2 nanorods, were evaluated as photocatalysts for the degradation of Bisphenol A (BPA). Fourier-transform infrared spectroscopy analysis revealed the successful incorporation of PANI into TiO2 by the appearance of peaks at 1577 and 1502 cm–1 that are due to the C═C and C–N stretch of the benzenoid or quinoid ring in PANI. Brunauer–Emmett–Teller analysis revealed that PANI/TiO2 had almost double the surface area of TiO2 (44.8999 m2/g vs 28.2179 m2/g). Transmission electron microscopy (TEM) analysis showed that TiO2 nanorods with different diameters were synthesized. The TEM analysis showed that a thin layer of PANI wrapped the TiO2 nanorods. X-ray photon spectroscopy survey scan of the PANI/TiO2 nanocomposite revealed the presence of C, O, Ti, and N. Photocatalytic activity evaluation under UV radiation through the effect of key parameters, including pH, contact time, dosage, and initial concentration of BPA, was carried out in batch studies. Within 80 min, 99.7% of 5 ppm BPA was attained using the 0.2 g/L PANI/TiO2 photocatalyst at pH 10. The quantum yield (QY) of these photocatalysts was evaluated to be 9.86 × 10–5 molecules/photon and 2.82 × 10–5 molecules/photon for PANI/TiO2 and TiO2, respectively. PANI/TiO2 showed better performance than as-synthesized TiO2 with a rate constant of 4.46 × 10–2 min–1 compared to 2.18 × 10–2 min–1. The rate of degradation of PANI/TiO2 was also superior to that of TiO2 (150 mmol/g/h vs 74.89 mmol/g/h). Nitrate ions increased the rate of degradation of BPA, while humic acid consistently inhibited the degradation of BPA. LC–MS analysis identified degradation products with m/z 213.1, 135.1, and 93.1. The PANI/TiO2 nanocomposite was reused up to five cycles with a removal of at least 80% in the fifth cycle. LC–MS results revealed three possible BPA degradation intermediates. LC–MS analysis identified degradation products which included protonated BPA, [C14H13O2+], and [C9H11O+]. The PANI/TiO2 nanocomposite demonstrated superior photocatalytic activity with respect to improved QY and figure of merit and lower energy consumption." @default.
• W3106509803 created "2020-11-23" @default.
• W3106509803 creator A5040943989 @default.
• W3106509803 creator A5071893976 @default.
• W3106509803 creator A5082222422 @default.
• W3106509803 date "2020-11-10" @default.
• W3106509803 modified "2023-10-14" @default.
• W3106509803 title "Polyaniline-Coated TiO₂ Nanorods for Photocatalytic Degradation of Bisphenol A in Water" @default.
• W3106509803 cites W112301332 @default.
• W3106509803 cites W1279311099 @default.
• W3106509803 cites W1959916946 @default.
• W3106509803 cites W1965498756 @default.
• W3106509803 cites W1970358298 @default.
• W3106509803 cites W1974769063 @default.
• W3106509803 cites W1975807435 @default.
• W3106509803 cites W1978663443 @default.
• W3106509803 cites W1978694944 @default.
• W3106509803 cites W1980846144 @default.
• W3106509803 cites W1983227646 @default.
• W3106509803 cites W1989380805 @default.
• W3106509803 cites W1997369633 @default.
• W3106509803 cites W2005007739 @default.
• W3106509803 cites W2007896057 @default.
• W3106509803 cites W2014104821 @default.
• W3106509803 cites W2014553168 @default.
• W3106509803 cites W2016262121 @default.
• W3106509803 cites W2019723274 @default.
• W3106509803 cites W2020337211 @default.
• W3106509803 cites W2022029287 @default.
• W3106509803 cites W2027174349 @default.
• W3106509803 cites W2030946379 @default.
• W3106509803 cites W2036213640 @default.
• W3106509803 cites W2037766564 @default.
• W3106509803 cites W2047438255 @default.
• W3106509803 cites W2051188427 @default.
• W3106509803 cites W2055662707 @default.
• W3106509803 cites W2055863116 @default.
• W3106509803 cites W2061588150 @default.
• W3106509803 cites W2065210115 @default.
• W3106509803 cites W2066632128 @default.
• W3106509803 cites W2089071157 @default.
• W3106509803 cites W2093217147 @default.
• W3106509803 cites W2103087590 @default.
• W3106509803 cites W2114729638 @default.
• W3106509803 cites W2124974994 @default.
• W3106509803 cites W2138453969 @default.
• W3106509803 cites W2170781880 @default.
• W3106509803 cites W2226094652 @default.
• W3106509803 cites W2282954994 @default.
• W3106509803 cites W2289577356 @default.
• W3106509803 cites W2304581664 @default.
• W3106509803 cites W2316242861 @default.
• W3106509803 cites W2318043664 @default.
• W3106509803 cites W2401753242 @default.
• W3106509803 cites W2403468684 @default.
• W3106509803 cites W2410781075 @default.
• W3106509803 cites W2461533163 @default.
• W3106509803 cites W2462795071 @default.
• W3106509803 cites W2470786767 @default.
• W3106509803 cites W2471345606 @default.
• W3106509803 cites W2499403452 @default.
• W3106509803 cites W2501397839 @default.
• W3106509803 cites W2510422562 @default.
• W3106509803 cites W2515275639 @default.
• W3106509803 cites W2528724445 @default.
• W3106509803 cites W2558943317 @default.
• W3106509803 cites W2575841248 @default.
• W3106509803 cites W2604835894 @default.
• W3106509803 cites W2605667852 @default.
• W3106509803 cites W2734927002 @default.
• W3106509803 cites W2761319174 @default.
• W3106509803 cites W2762967552 @default.
• W3106509803 cites W2766001823 @default.
• W3106509803 cites W2766266023 @default.
• W3106509803 cites W2767855070 @default.
• W3106509803 cites W2789776786 @default.
• W3106509803 cites W2791530485 @default.
• W3106509803 cites W2881926850 @default.
• W3106509803 cites W2883443325 @default.
• W3106509803 cites W2889624369 @default.
• W3106509803 cites W2898414185 @default.
• W3106509803 cites W2910856796 @default.
• W3106509803 cites W3000380436 @default.
• W3106509803 cites W304232353 @default.
• W3106509803 cites W4382585131 @default.
• W3106509803 cites W756567658 @default.
• W3106509803 cites W777138203 @default.
• W3106509803 doi "https://doi.org/10.1021/acsomega.0c00628" @default.
• W3106509803 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7689664" @default.
• W3106509803 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33251400" @default.
• W3106509803 hasPublicationYear "2020" @default.
• W3106509803 type Work @default.
• W3106509803 sameAs 3106509803 @default.
• W3106509803 citedByCount "45" @default.
• W3106509803 countsByYear W31065098032021 @default.
• W3106509803 countsByYear W31065098032022 @default.
• W3106509803 countsByYear W31065098032023 @default.
• W3106509803 crossrefType "journal-article" @default.

• next