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- W3106534898 abstract "A concise method for the construction of heteroaryl-fused phenazines was developed via PIFA-BF3·Et2O-mediated oxidative coupling of di-heteroarylated quinoxalines for the first time. Synthesis of mono- and di-heteroarylation of quinoxaline was performed effectively using only LiTMP reagent under transition metal-free conditions and without the use of halogen-containing starting compounds. In addition, nonsymmetrical di-heteroarylated quinoxalines were synthesized through reheteroarylation of mono-heteroarylated quinoxalines in the same way. Oxidation of the saturated compounds formed after heteroarylation was easily accomplished with iodine. The UV–vis absorption and fluorescence features of some compounds were examined." @default.
- W3106534898 created "2020-11-23" @default.
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- W3106534898 date "2020-11-13" @default.
- W3106534898 modified "2023-09-25" @default.
- W3106534898 title "Transition Metal-Free Heteroarylation of Quinoxaline: Construction of Heteroaryl-Fused Phenazines by Oxidative Coupling" @default.
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- W3106534898 doi "https://doi.org/10.1021/acs.joc.0c02252" @default.
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