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- W3106552904 endingPage "9734" @default.
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- W3106552904 abstract "The electrophilic alkylthiolation of alkenes, initiated by dimethyl(methylthio)sulfonium salts and the subsequent addition of various heteronucleophilies has been well-established. Regarding the use of carbon nucleophiles, however, only carefully designed sp-type carbon sources have been successfully applied. We herein present our findings on the methylthiolation of alkenes with dimethyl(methylthio)sulfonium trifluoromethanesulfonate, followed by carbon–carbon bond formation in the presence of organozinc reagents, thus achieving a catalyst-free protocol toward to the carbosulfenylation of alkenes." @default.
- W3106552904 created "2020-12-07" @default.
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- W3106552904 date "2020-11-30" @default.
- W3106552904 modified "2023-10-16" @default.
- W3106552904 title "Carbosulfenylation of Alkenes with Organozinc Reagents and Dimethyl(methylthio)sulfonium Trifluoromethanesulfonate" @default.
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- W3106552904 doi "https://doi.org/10.1021/acs.orglett.0c03810" @default.
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