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- W3106593916 abstract "Abstract Hybrid improper ferroelectric Ca 3 Ti 2 O 7 and Ca 3 Ti 19 Ru 0.1 O 7 ceramics were successfully synthesized by conventional solid-state reaction method. Two strongest diffraction peaks located around 2 θ = 33° shifted towards the lower angle region with Ru substitution, reflecting structure variation. Grain growth and higher oxygen vacancy concentration after doping resulted in a reduction in the coercive field about 20 kV/cm. Optical bandgap estimated by UV-vis diffuse reflectance (DR) spectrum and X-ray photoelectron spectroscopy (XPS) valence band spectra showed a decreasing trend due to the existence of impurity energy level upon Ru doping, which was consistent with the results of first-principles calculations. The origin of the unexpected induced magnetic moments in Ru-dope Ca 3 Ti 2 O 7 is also discussed." @default.
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- W3106593916 date "2020-11-28" @default.
- W3106593916 modified "2023-10-13" @default.
- W3106593916 title "Novel optical properties and induced magnetic moments in Ru-doped hybrid improper ferroelectric Ca3Ti2O7" @default.
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- W3106593916 doi "https://doi.org/10.1007/s40145-020-0425-2" @default.
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