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- W3106651119 endingPage "120174" @default.
- W3106651119 startingPage "120174" @default.
- W3106651119 abstract "A new zirconium-based metal-organic polyhedron (Zr-MOP-1) was successfully synthesized from Bis(cyclopentadienyl)zirconium dichloride and 2,5-pyridinedicarboxylic acid under solvothermal condition. It was characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis and infrared spectroscopy. Four trinuclear zirconocene building blocks as well as six linear carboxylate ligands give rise to its tetrahedral configuration. Interestingly, Zr-MOP-1 possesses considerable reversible iodine sorption performance in organic phase featuring an optimal adsorption capacity of 283 mg g−1. The related kinetics absorption and desorption process were fully explored in detail by multiple complementary experiments and the adsorbed iodine species (I− and I3−) in Zr-MOP-1 had been further identified through crystallographic analyses. This work provides new possibilities for developing new and functional zirconium-based molecular cages materials." @default.
- W3106651119 created "2020-12-07" @default.
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- W3106651119 date "2021-02-01" @default.
- W3106651119 modified "2023-10-17" @default.
- W3106651119 title "Synthesis, crystal structure and iodine capture of Zr-based metal-organic polyhedron" @default.
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- W3106651119 doi "https://doi.org/10.1016/j.ica.2020.120174" @default.
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