FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3106689954> ?p ?o ?g. }

• W3106689954 endingPage "247" @default.
• W3106689954 startingPage "237" @default.
• W3106689954 abstract "Home prepared TiO2 photocatalysts were prepared from TiCl4 precursor in the absence and presence of HCl (1−6 M), HNO3 (1 M) or H2SO4 (1 M) at room temperature (RT), 60 or 100 °C. The TiO2 catalysts were characterised by XRD, BET, SEM and TGA techniques. TiO2 catalyst could not form at low temperature (up to 60 °C) in the presence of H2SO4. Just rutile phase was obtained for all TiO2 samples prepared at RT and 60 °C in HCl or HNO3. At 100 °C mainly both brookite and rutile phases were obtained in the presence of HCl or HNO3, whilst mainly anatase phase appeared in the presence of H2SO4. Nanorod structured TiO2 was formed in the presence of 1 M HCl or HNO3 at RT and 60 °C. The prepared TiO2 catalysts were used for partial oxidation of 3-pyridinemethanol to 3-pyridinemethanal and vitamin B3 in water under UVA irradiation. Moreover, photocatalytic oxidation of 3-picoline, precursor of 3-pyridinemethanol, was also performed, but much lower product selectivity values were obtained with respect to 3-pyridinemethanol oxidation. However, selective 3-picoline oxidation could be performed at pH 2 with low activity. Degussa P25 was used for comparison and almost all home prepared catalysts showed a higher selectivity, but they showed to be less active than Degussa P25. The high selectivity of the home prepared samples was not due to the type of TiO2 phase, but mainly to the hydrophilicity of the TiO2 surface which allowed desorption of valuable products instead of their over-oxidation." @default.
• W3106689954 created "2020-12-07" @default.
• W3106689954 creator A5010564165 @default.
• W3106689954 creator A5074070150 @default.
• W3106689954 date "2021-11-01" @default.
• W3106689954 modified "2023-10-03" @default.
• W3106689954 title "Partial photocatalytic oxidations of 3-pyridinemethanol and 3-picoline by TiO2 prepared in HCl, HNO3 and H2SO4 at different temperatures" @default.
• W3106689954 cites W1449285358 @default.
• W3106689954 cites W1829643206 @default.
• W3106689954 cites W1963775146 @default.
• W3106689954 cites W1971008178 @default.
• W3106689954 cites W1975109963 @default.
• W3106689954 cites W1991443792 @default.
• W3106689954 cites W2003638436 @default.
• W3106689954 cites W2009414392 @default.
• W3106689954 cites W2012117213 @default.
• W3106689954 cites W2022828720 @default.
• W3106689954 cites W2023770981 @default.
• W3106689954 cites W2028919804 @default.
• W3106689954 cites W2031722493 @default.
• W3106689954 cites W2035305725 @default.
• W3106689954 cites W2040695727 @default.
• W3106689954 cites W2041375067 @default.
• W3106689954 cites W2041667504 @default.
• W3106689954 cites W2044743560 @default.
• W3106689954 cites W2046537181 @default.
• W3106689954 cites W2051755057 @default.
• W3106689954 cites W2053892354 @default.
• W3106689954 cites W2055308461 @default.
• W3106689954 cites W2058270577 @default.
• W3106689954 cites W2060534472 @default.
• W3106689954 cites W2071067641 @default.
• W3106689954 cites W2073290435 @default.
• W3106689954 cites W2073650880 @default.
• W3106689954 cites W2075022969 @default.
• W3106689954 cites W2090515712 @default.
• W3106689954 cites W2092192733 @default.
• W3106689954 cites W2092746509 @default.
• W3106689954 cites W2099811794 @default.
• W3106689954 cites W2118030354 @default.
• W3106689954 cites W2121871844 @default.
• W3106689954 cites W2138405719 @default.
• W3106689954 cites W2138737817 @default.
• W3106689954 cites W2144276565 @default.
• W3106689954 cites W2154903153 @default.
• W3106689954 cites W2170848987 @default.
• W3106689954 cites W2275657277 @default.
• W3106689954 cites W2317825609 @default.
• W3106689954 cites W2330537669 @default.
• W3106689954 cites W2331611068 @default.
• W3106689954 cites W2468149489 @default.
• W3106689954 cites W2503374263 @default.
• W3106689954 cites W2520610428 @default.
• W3106689954 cites W2527282769 @default.
• W3106689954 cites W2535769837 @default.
• W3106689954 cites W2550064513 @default.
• W3106689954 cites W2554035864 @default.
• W3106689954 cites W2571824444 @default.
• W3106689954 cites W2579919965 @default.
• W3106689954 cites W2612898279 @default.
• W3106689954 cites W2758882979 @default.
• W3106689954 cites W2889065908 @default.
• W3106689954 cites W2902056409 @default.
• W3106689954 cites W2912806909 @default.
• W3106689954 cites W2983793768 @default.
• W3106689954 doi "https://doi.org/10.1016/j.cattod.2020.11.004" @default.
• W3106689954 hasPublicationYear "2021" @default.
• W3106689954 type Work @default.
• W3106689954 sameAs 3106689954 @default.
• W3106689954 citedByCount "4" @default.
• W3106689954 countsByYear W31066899542022 @default.
• W3106689954 countsByYear W31066899542023 @default.
• W3106689954 crossrefType "journal-article" @default.
• W3106689954 hasAuthorship W3106689954A5010564165 @default.
• W3106689954 hasAuthorship W3106689954A5074070150 @default.
• W3106689954 hasConcept C110686534 @default.
• W3106689954 hasConcept C118792377 @default.
• W3106689954 hasConcept C13965031 @default.
• W3106689954 hasConcept C161790260 @default.
• W3106689954 hasConcept C178790620 @default.
• W3106689954 hasConcept C179104552 @default.
• W3106689954 hasConcept C185592680 @default.
• W3106689954 hasConcept C2776272617 @default.
• W3106689954 hasConcept C2777379063 @default.
• W3106689954 hasConcept C2777402863 @default.
• W3106689954 hasConcept C2777889555 @default.
• W3106689954 hasConcept C2779299574 @default.
• W3106689954 hasConcept C2779485729 @default.
• W3106689954 hasConcept C27923307 @default.
• W3106689954 hasConcept C65165184 @default.
• W3106689954 hasConceptScore W3106689954C110686534 @default.
• W3106689954 hasConceptScore W3106689954C118792377 @default.
• W3106689954 hasConceptScore W3106689954C13965031 @default.
• W3106689954 hasConceptScore W3106689954C161790260 @default.
• W3106689954 hasConceptScore W3106689954C178790620 @default.
• W3106689954 hasConceptScore W3106689954C179104552 @default.
• W3106689954 hasConceptScore W3106689954C185592680 @default.
• W3106689954 hasConceptScore W3106689954C2776272617 @default.

• next