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- W3107349867 abstract "Current work reports the first investigation on the nanocomposites of molybdenum and zinc oxide [MoO3@ZnO] synthesized via chemosynthetic and biomimetic routes. Chemosynthetic and biomimetic MoO3@ZnO nanocomposites expressed a direct band gap of 4.5 and 3.5 eV, explored via ultraviolet spectrophotometry capped with organic functional groups shown by Fourier transform infra-red spectroscopy. Polycrystalline patterns expressing average crystallite sizes of 36.9 and 22.5 nm for nanocomposites were revealed by X-ray diffraction. Nanocomposites expressed capsule and spherical shapes shown by field emission scanning electron micrographs with strong signals for Mo, Zn and O shown via energy dispersive X-ray spectroscopy. Raman spectroscopy revealed the successful synthesis of the MoO3@ZnO nanocomposite. Electrochemical studies included cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Redox peaks revealed the pseudo-capacitive behavior shown. EIS Nyquist plot with an arc radius pointed the existence of resistance mechanism arising from interfacial layer taking place at the electrode MoO3@ZnO nanocomposite surficial region with charge transfer resistance Rct of = 22.02 Ω. The semi-conducting and capacitive behavior of the biogenic nanocomposite makes it a future candidate for utilization in solar cells and other photovoltaic devices marked by profound sustainability, eco-friendliness, economic viability and scalability in comparison to environmentally damaging chemosynthetic solvo-thermal pathway." @default.
- W3107349867 created "2020-12-07" @default.
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- W3107349867 date "2021-04-01" @default.
- W3107349867 modified "2023-10-17" @default.
- W3107349867 title "Biomimetic [MoO3@ZnO] semiconducting nanocomposites: Chemo-proportional fabrication, characterization and energy storage potential exploration" @default.
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- W3107349867 doi "https://doi.org/10.1016/j.renene.2020.11.115" @default.
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