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- W3107564293 abstract "Desulfonylative alkylation of N -tosyl-1,2,3-triazoles under metal-free conditions leading to β-triazolylenones is reported here. The present study encompasses the synthesis of triazoles with a new substitution pattern in a single step from cyclic 1,3-dicarbonyl compounds and N -tosyl triazole in moderate to high yields. Our synthesis takes place with complete regioselectivity as confirmed by crystallographic analysis which is rationalized by a suitable mechanistic proposal. This method provides an efficient, versatile and straightforward strategy towards the synthesis of new functionalized 1,2,3-triazoles." @default.
- W3107564293 created "2020-12-07" @default.
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- W3107564293 date "2021-03-31" @default.
- W3107564293 modified "2023-09-29" @default.
- W3107564293 title "Synthesis of β-triazolylenones via metal-free desulfonylative alkylation of <i>N</i>-tosyl-1,2,3-triazoles" @default.
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- W3107564293 doi "https://doi.org/10.3762/bjoc.17.66" @default.
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