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- W3107651922 endingPage "1829" @default.
- W3107651922 startingPage "1812" @default.
- W3107651922 abstract "Abstract Fe oxidation/reduction reactions play a fundamental role in a wide variety of geological processes. In natural materials, Fe redox state commonly varies across small spatial scales at reaction interfaces, yet the approaches available for quantitatively mapping the Fe redox state at the microscale are limited. We have designed an optimized synchrotron-based X-ray spectroscopic approach that allows microscale quantitative mapping of Fe valence state by extending the Fe XANES pre-edge technique. An area of interest is mapped at nine energies between 7109–7118 eV and at 7200 eV, allowing reconstruction, baseline subtraction, and integration of the pre-edge feature to determine Fe(III)/ΣFe with 2 μm spatial resolution. By combining the Fe redox mapping approach with hyperspectral Raman mineralogy mapping, the Fe oxidation state distributions of the major mineral phases are revealed. In this work, the method is applied to a partially serpentinized peridotite with various Fe-bearing secondary mineral phases to trace the Fe transformations and redox changes that occurred during its alteration. Analysis with the Fe redox mapping technique revealed that the peridotite contained relict olivine with abundant Fe(II), while serpentine, pyroaurite, and another hydroxide phase are secondary mineral reservoirs of Fe(III). Although serpentine is not Fe-rich, it contained approximately 74% ± 14% Fe(III)/ΣFe. These analytical results are integral to interpreting the sequence of alteration reactions; serpentinization of primary olivine formed Fe(II)-rich brucite and oxidized serpentine, which could have contributed to H2 production during serpentinization. Subsequent weathering by oxidizing, CO2-bearing fluids led to the partial carbonation and oxidation of brucite, forming pyroaurite and a hydroxide phase containing dominantly Fe(III). This Fe redox imaging approach is applicable to standard petrographic thin sections or grain mounts and can be applied to various geologic and biogeochemical systems." @default.
- W3107651922 created "2020-12-07" @default.
- W3107651922 creator A5007844044 @default.
- W3107651922 creator A5019579681 @default.
- W3107651922 creator A5025724408 @default.
- W3107651922 creator A5063645410 @default.
- W3107651922 date "2020-12-01" @default.
- W3107651922 modified "2023-09-27" @default.
- W3107651922 title "Quantitative microscale Fe redox imaging by multiple energy X-ray fluorescence mapping at the Fe<i>K</i>pre-edge peak" @default.
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