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• W3107783034 endingPage "622" @default.
• W3107783034 startingPage "615" @default.
• W3107783034 abstract "The kinetics of the formation of the light orange–coloured complex [Ru(CN) 5 D-PA] 3− are studied spectrophotometrically through substitution of a coordinated H 2 O molecule in aquapentacyanoruthenate(II) [Ru(CN) 5 OH 2 ] 3− by interaction with D-penicillamine [D-PA] in aqueous medium at 490 nm (λ max of [Ru(CN) 5 D-PA] 3− ). The reaction is monitored under pseudo-first-order conditions, taking [D-PA] in excess over [Ru(CN) 5 OH 2 3− ]. The effects of various reaction parameters on the rate of the reaction are investigated. Experimental observations reveal that the variation in [D-PA] obeyed the first-order rate law while it is found to be invariant with [Ru(CN) 5 OH 2 3− ] in the whole experimental range. With ionic strength variation, as the reaction advances a decrease in the reaction rate is noticed. The product stoichiometry is assigned as 1:1. The ease of substitution at an H 2 O molecule in [Ru(CN) 5 OH 2 3− ] is considered on the basis of the electronic effect generated through interactions of the M–OH 2 bond. A provisional mechanism based on the calculated results is proposed based on the slowest step of the reaction." @default.
• W3107783034 created "2020-12-07" @default.
• W3107783034 creator A5025583339 @default.
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• W3107783034 date "2020-11-24" @default.
• W3107783034 modified "2023-10-16" @default.
• W3107783034 title "The kinetics and mechanism of the ligand substitution reaction of aquapentacyanoruthenate(II) with <scp>d</scp>-penicillamine in aqueous medium" @default.
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• W3107783034 doi "https://doi.org/10.1177/1747519820961015" @default.
• W3107783034 hasPublicationYear "2020" @default.
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