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- W3108062545 endingPage "119249" @default.
- W3108062545 startingPage "119249" @default.
- W3108062545 abstract "A newly designed Schiff base probe JN has been synthesized. It is highly selective and sensitive towards Al3+ in nearly 100% aqueous medium by exhibiting a dramatic “turn-on” fluorescence response at 495 nm (λex = 450 nm). The sensing mechanism of JN towards Al3+ ions was proposed as the combination of PET, ICT, ESIPT, and CHEF processes according to spectra studies and theory calculations. The in situ generated mononuclear Al(III) complex JN-Al3+ could sequentially detect PPi ions by turn-off fluorescence response. The selectivity and sensitivity of the JN-Al3+ complex towards PPi ions are based on demetalization process. Interestingly, the fact that Al3+ can bind with 1, 2, or 3 PPi has been revealed by HRMS study. The probes JN and JN-Al3+ complexes were able to capture Al3+ and PPi ions, respectively, as demonstrated by fluorescence imaging of the adult zebrafish and onion inner epidermal cells samples." @default.
- W3108062545 created "2020-12-07" @default.
- W3108062545 creator A5004471880 @default.
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- W3108062545 date "2021-04-01" @default.
- W3108062545 modified "2023-10-18" @default.
- W3108062545 title "Selective sensing of PPi by fluorogenic Al(III)-probe complex in aqueous medium" @default.
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- W3108062545 doi "https://doi.org/10.1016/j.saa.2020.119249" @default.
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