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• W3108872605 abstract "The Smoluchowski’s coagulation rate coefficient (kc-S) has been used for decades notwithstanding its predictions are not always consistent with experimental data. In this work, kc-S and Herrera-Ordóñez (kc-HO) models, were modified and combined to obtain a hybrid equation kc-h for the rate coefficient of rapid coagulation. Modification of kc-S consisted in adapting the concepts of diffusion-reaction, such as effectiveness factor F, to the case of particle coagulation which is considered a pseudo-reaction. Unlike the deterministic and stochastic approaches, the hybrid model kc-h can fit experimental data for the effects of size and concentration of particles, on kc, using only one adjustable parameter value for all particle sizes. The higher predictability of kc-h suggests that their assumptions are more realistic. The behavior of F indicates that the fusion of relatively large particles is more effective than that of small particles to produce the sink effect." @default.
• W3108872605 created "2020-12-07" @default.
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• W3108872605 date "2021-03-01" @default.
• W3108872605 modified "2023-09-30" @default.
• W3108872605 title "Coagulation rate coefficient in colloidal systems: A hybrid stochastic-deterministic theory" @default.
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• W3108872605 doi "https://doi.org/10.1016/j.ces.2020.116289" @default.
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