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- W3109568732 abstract "<p>Although many impressive metallo-supramolecular architectures have been reported, they tend towards high symmetry structures and avoid extraneous functionality to ensure high-fidelity in the self-assembly process. This minimalist approach, however, limits the range of accessible structures and thus their potential applications. Herein is described a late stage diversification strategy towards ligand scaffolds that are both low symmetry and incorporate exohedral functional moieties. Key to this design is the use of CuAAC chemistry, as the triazole is capable of acting as both a coordinating heterocycle and a tether between the ligand framework and functional unit simultaneously. In this manner a common precursor was used to generate ligands with various functionalities, allowing control of electronic properties, whilst maintaining the core structure of the resultant <i>cis</i>-Pd<sub>2</sub>L<sub>4</sub> nanocage assemblies. The isostructural nature of the scaffold frameworks enabled formation of combinatorial libraries from the self-assembly of ligand mixtures, generating multi-functional, low-symmetry architectures.</p>" @default.
- W3109568732 created "2020-12-07" @default.
- W3109568732 creator A5029733854 @default.
- W3109568732 date "2020-11-17" @default.
- W3109568732 modified "2023-10-16" @default.
- W3109568732 title "Late Stage Diversification of an Unsymmetrical Ligand Scaffold for Multi-functional cis-Pd2L4 Nanocage Libraries" @default.
- W3109568732 doi "https://doi.org/10.26434/chemrxiv.13246715.v1" @default.
- W3109568732 hasPublicationYear "2020" @default.
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