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- W3109643066 abstract "Abstract Axially coordinated oligomer of ferrocene based Sn(IV) porphyrin with C60 was synthesized and characterized by the common spectral method and thermogravimetric analysis. The oligomer aggregated into irregular block structure in solid state from observation of scanning electron microscope. According to UV–visible absorption spectra, there was almost no electronic interaction in the ground state among the photoactive components in the oligomer. However, the nanosecond transient absorption spectra and steady-state fluorescence spectra experiments indicated that efficient photoinduced electron transfer among C60, excited Sn(IV) porphyrin, and ferrocene had occurred, which resulted in forming the final charge-separated state with long time of 14 μs in benzonitrile. In addition, a prompt and stable photocurrent was generated in the photovoltaic devices upon irradiation by monochromatic light of λex = 429 nm." @default.
- W3109643066 created "2020-12-07" @default.
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- W3109643066 date "2021-01-01" @default.
- W3109643066 modified "2023-09-24" @default.
- W3109643066 title "Axially coordinated oligomer of ferrocene-based porphyrin with fullerene C60 for spectroscopic and photocurrent studies" @default.
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- W3109643066 doi "https://doi.org/10.1016/j.synthmet.2020.116635" @default.
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