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- W3109687126 abstract "In the title polymeric Zn II compound, [Zn(C 8 H 7 O 3 ) 2 (C 12 H 12 N 2 )] n , the Zn cation is coordinated by two N atoms from 1,2-bis(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hydroxy(phenyl)acetate] anions in a slightly distorted octahedral coordination geometry. The 1,2-bis(pyridin-4-yl)ethane unit bridges two Zn II cations, related by an inversion centre, to form a polymeric chain along [110]. The crystal structure features extensive O—H...O and weak C—H ...O hydrogen bonds, with C—H ... π interactions and π–π interactions also being present. The centroid–centroid distance between the phenyl ring of the mandelate group and the 1,2-bis(pyridine-4-yl)ethane moiety is 4.951 (2) Å. The 1,2-bis(pyridin-4-yl)ethane ligand is disordered over two positions, with a refined occupancy of 0.578 (14) for the major component." @default.
- W3109687126 created "2020-12-07" @default.
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- W3109687126 date "2020-11-24" @default.
- W3109687126 modified "2023-09-25" @default.
- W3109687126 title "Crystal structure of the coordination polymer catena-poly[[bis[hydroxy(phenyl)acetato-κ2 O 1,O 2]zinc(II)]-μ2-1,2-bis(pyridin-4-yl)ethane-κ2 N:N′]" @default.
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- W3109687126 doi "https://doi.org/10.1107/s2056989020014322" @default.
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