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• W3109941260 abstract "The performance, selectivity, recovery, and reusability of high metal loading commercial Ni66 ± 5%/SiO2–Al2O3 catalyst were studied in renewable hydrocarbon synthesis from low cost raw material pretreated soapstock (TS) by solvent-free one-pot hydrotreatment (HT). TS was extracted from rapeseed oil chemical refining by-product/waste soapstock (SS) by developed simple treatment method. The catalyst was characterized by FE-SEM, TEM, XRF, XRD, and N2 sorption analysis. Feedstock, liquid, and gaseous products were analyzed by FT-IR, GC-FID, GC-MS, GC-TCD, and CHNS elemental analysis. The effect of initial H2 pressure (2–8 MPa), catalyst amount (3–9%), reaction temperature (280–340 °C), and residence time (15–60 min) on hydrocarbon production were investigated. Combustible gases and pure marketable linear saturated hydrocarbons with high yield 79.1%, calorific value 47.22 MJ/kg, C/H ratio 5.6, and n-C17 content 82.7% were successfully produced from TS using minimum effective catalyst amount and reaction conditions: 5%, 6 MPa, 320 °C, and 30 min." @default.
• W3109941260 created "2020-12-07" @default.
• W3109941260 creator A5039730248 @default.
• W3109941260 date "2021-02-01" @default.
• W3109941260 modified "2023-10-12" @default.
• W3109941260 title "Production of renewable hydrocarbons from vegetable oil refining by-product/waste soapstock over selective sulfur-free high metal loading SiO2–Al2O3 supported Ni catalyst via hydrotreatment" @default.
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• W3109941260 doi "https://doi.org/10.1016/j.jclepro.2020.125306" @default.
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