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- W3110539219 abstract "1,4-Naphthoquinone (NQ) undergoes a two electron and two proton redox process in one step at a potential of −0.05 V (vs Ag/AgCl) in 0.05 M H2SO4 aqueous solution. Its heterogeneous electron transfer rate constant is comparable to those of electrochemically reversible redox-active molecules. Therefore, NQ is a potential electrode-active material candidate in acidic aqueous electrolyte. Simple nucleophilic substitution of 2-bromo-1,4-naphthoquinone and poly(allylamine) yields NQ-substituted poly(allylamine) (PNQ), enabling us to adjust the hydrophilicity of the redox polymer according to the NQ introduction rate. A polymer–air secondary battery composed of the PNQ anode, the Pt/C cathode, and 0.05 M H2SO4 aqueous electrolyte displayed high cyclability (>100 cycles) and C-rate capability (∼15 C) with a moderate voltage of 0.8 V during discharging." @default.
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- W3110539219 date "2020-12-03" @default.
- W3110539219 modified "2023-10-17" @default.
- W3110539219 title "Charge- and Proton-Storage Capability of Naphthoquinone-Substituted Poly(allylamine) as Electrode-Active Material for Polymer–Air Secondary Batteries" @default.
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- W3110539219 doi "https://doi.org/10.1021/acsaem.0c02178" @default.
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