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• W3110588115 startingPage "111303" @default.
• W3110588115 abstract "It is very challenging to improve the catalytic activity of Pd-based catalysts since the strong CO chemisorbtion on Pd leading to poor activity at ambient temperature. Herein, we report that modulating the exposed facet of α-Fe2O3 nanocrystalline, i.e. (110), (001) and (012), is a facial way to improve catalytic activity for acetylene dicarbonylation. The obtained Pd/HNRs catalyst with exposed (110) crystal plane give a 100 % acelyene conversion at room temperature. Through a combination of X-ray photoelectron spectroscopy and H2-TPR, we demonstrate that the Pd-HNRs interaction leads to the weaker CO absorption strength. Meanwhile, the kinetics studies demonstrate that α-Fe2O3 oxide extends the reaction routine due the improved activity of C2H2, with the help of moderately acidic sites, then overcome the inhibition of the C2H2 activating in pure Pd species. Moreover, we verified a satisfying reusability over the Pd/HNRs catalyst, being used in up to eight consecutive cycles without loss of activity or selectivity significantly." @default.
• W3110588115 created "2020-12-07" @default.
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• W3110588115 date "2021-01-01" @default.
• W3110588115 modified "2023-10-03" @default.
• W3110588115 title "Synergistic effect of hematite facet and Pd nanocluster for enhanced acetylene dicarbonylation" @default.
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• W3110588115 doi "https://doi.org/10.1016/j.mcat.2020.111303" @default.
• W3110588115 hasPublicationYear "2021" @default.
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