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- W3111373192 endingPage "10747" @default.
- W3111373192 startingPage "10736" @default.
- W3111373192 abstract "A symmetrical molecular array has been synthesized comprising a central zinc(II) 5,10,15,20-tetraphenylporphyrin with identical boron dipyrromethene (BODIPY) units appended at each of the meso sites. Excitation of any subunit causes a cascade of electronic energy-transfer steps, ultimately leading to the BODIPY triplet-excited state in high yield. Coincidentally, the triplet energy levels of the zinc(II) porphyrin and BODIPY appendage are closely balanced such that an equilibrium is established at both 77 K and room temperature. This fast equilibration allows global distribution of the triplet exciton around the array, leading to a significantly increased capture volume for bimolecular quenching and a substantial increase in the rate constant for bimolecular triplet–triplet annihilation. The corresponding free-base porphyrin analogue does not favor triplet exciton decentralization because of the large disparity in the electronic energy levels." @default.
- W3111373192 created "2020-12-21" @default.
- W3111373192 creator A5011228101 @default.
- W3111373192 creator A5038705766 @default.
- W3111373192 creator A5057505787 @default.
- W3111373192 date "2020-12-09" @default.
- W3111373192 modified "2023-09-27" @default.
- W3111373192 title "Triplet Distribution in a Symmetrical Zinc(II) Porphyrin–BODIPY Pentameric Array" @default.
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