Matches in SemOpenAlex for { <https://semopenalex.org/work/W3111551336> ?p ?o ?g. }
- W3111551336 endingPage "218" @default.
- W3111551336 startingPage "206" @default.
- W3111551336 abstract "Herein, one kind of neutral chiral zirconium metal-organic framework (Zr-MOF) was reported from the porphyrinic MOF (PMOF) family with a metallolinker (MnIII-porphyrin) as the achiral polytopic linker [free base tetrakis(4-carboxyphenyl)porphyrin] and chiral anions. Achiral Zr-MOF was chiralized through the exchange of primitive anions with new chiral organic anions (postsynthetic exchange). This chiral functional porphyrinic MOF (CPMOF) was characterized by several techniques such as powder X-ray diffraction, Fourier transform infrared spectroscopy, ultraviolet-visible spectroscopy, 1H NMR, energy-dispersive X-ray spectroscopy, scanning electron microscopy, and Brunauer-Emmett-Teller measurements. In the resulting structure, there are two active metal sites as Lewis acid centers (Zr and Mn) and chiral species as Bronsted acid sites along with their cooperation as nucleophiles. This CPMOF shows considerable bimodal porosity with high surface area and stability. Additionally, its ability was investigated in asymmetric catalyses of prochiral substrates. Interactions between framework chiral species and prochiral substrates have large impacts on the catalytic ability and chirality induction. This chiral catalyst proceeded asymmetric epoxidation and CO2 fixation reactions at lower pressure with high enantioselectivity due to Lewis acids and chiral auxiliary nucleophiles without significant loss of activity up to the sixth step of consecutive cycles of reusability. Observations revealed that chiralization of Zr-MOF could happen by a succinct strategy that can be a convenient method to design chiral MOFs." @default.
- W3111551336 created "2020-12-21" @default.
- W3111551336 creator A5024817634 @default.
- W3111551336 creator A5064125448 @default.
- W3111551336 date "2020-12-13" @default.
- W3111551336 modified "2023-10-17" @default.
- W3111551336 title "Construction of an Asymmetric Porphyrinic Zirconium Metal–Organic Framework through Ionic Postchiral Modification" @default.
- W3111551336 cites W1771959753 @default.
- W3111551336 cites W1964823769 @default.
- W3111551336 cites W1967109824 @default.
- W3111551336 cites W1979110830 @default.
- W3111551336 cites W1980729286 @default.
- W3111551336 cites W1985540944 @default.
- W3111551336 cites W1989118706 @default.
- W3111551336 cites W1993146835 @default.
- W3111551336 cites W2002041482 @default.
- W3111551336 cites W2002799357 @default.
- W3111551336 cites W2010278674 @default.
- W3111551336 cites W2013080921 @default.
- W3111551336 cites W2016539884 @default.
- W3111551336 cites W2019941215 @default.
- W3111551336 cites W2021523927 @default.
- W3111551336 cites W2024459961 @default.
- W3111551336 cites W2027743899 @default.
- W3111551336 cites W2044683783 @default.
- W3111551336 cites W2047774247 @default.
- W3111551336 cites W2062269633 @default.
- W3111551336 cites W2063496385 @default.
- W3111551336 cites W2072049621 @default.
- W3111551336 cites W2072701796 @default.
- W3111551336 cites W2078122806 @default.
- W3111551336 cites W2090352689 @default.
- W3111551336 cites W2090748133 @default.
- W3111551336 cites W2138046088 @default.
- W3111551336 cites W2141939342 @default.
- W3111551336 cites W2153799675 @default.
- W3111551336 cites W2190558763 @default.
- W3111551336 cites W2261388085 @default.
- W3111551336 cites W2283564633 @default.
- W3111551336 cites W2312340490 @default.
- W3111551336 cites W2322405345 @default.
- W3111551336 cites W2322759533 @default.
- W3111551336 cites W2322788072 @default.
- W3111551336 cites W2342957257 @default.
- W3111551336 cites W2345741510 @default.
- W3111551336 cites W2418360140 @default.
- W3111551336 cites W2547478084 @default.
- W3111551336 cites W2584192599 @default.
- W3111551336 cites W2586464769 @default.
- W3111551336 cites W2597419805 @default.
- W3111551336 cites W2621605813 @default.
- W3111551336 cites W2729892695 @default.
- W3111551336 cites W2763857535 @default.
- W3111551336 cites W2765122126 @default.
- W3111551336 cites W2779937803 @default.
- W3111551336 cites W2780958320 @default.
- W3111551336 cites W2790425116 @default.
- W3111551336 cites W2796276717 @default.
- W3111551336 cites W2807575223 @default.
- W3111551336 cites W2808527632 @default.
- W3111551336 cites W2883327357 @default.
- W3111551336 cites W2887947396 @default.
- W3111551336 cites W289038359 @default.
- W3111551336 cites W2900937577 @default.
- W3111551336 cites W2914053914 @default.
- W3111551336 cites W2946245441 @default.
- W3111551336 cites W2949571855 @default.
- W3111551336 cites W2949934645 @default.
- W3111551336 cites W2952974269 @default.
- W3111551336 cites W2954551512 @default.
- W3111551336 cites W2965780017 @default.
- W3111551336 cites W2966359290 @default.
- W3111551336 cites W2970184839 @default.
- W3111551336 cites W2996797507 @default.
- W3111551336 cites W3001657240 @default.
- W3111551336 cites W3095214227 @default.
- W3111551336 cites W3143879557 @default.
- W3111551336 doi "https://doi.org/10.1021/acs.inorgchem.0c02811" @default.
- W3111551336 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33307674" @default.
- W3111551336 hasPublicationYear "2020" @default.
- W3111551336 type Work @default.
- W3111551336 sameAs 3111551336 @default.
- W3111551336 citedByCount "18" @default.
- W3111551336 countsByYear W31115513362021 @default.
- W3111551336 countsByYear W31115513362022 @default.
- W3111551336 countsByYear W31115513362023 @default.
- W3111551336 crossrefType "journal-article" @default.
- W3111551336 hasAuthorship W3111551336A5024817634 @default.
- W3111551336 hasAuthorship W3111551336A5064125448 @default.
- W3111551336 hasConcept C145148216 @default.
- W3111551336 hasConcept C178790620 @default.
- W3111551336 hasConcept C179104552 @default.
- W3111551336 hasConcept C185592680 @default.
- W3111551336 hasConcept C188027245 @default.
- W3111551336 hasConcept C2182769 @default.
- W3111551336 hasConcept C534791751 @default.
- W3111551336 hasConcept C544153396 @default.
- W3111551336 hasConceptScore W3111551336C145148216 @default.