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- W3111662104 endingPage "9517" @default.
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- W3111662104 abstract "Monoallylic 1,3- and 1,5-diols undergo Re2O7-mediated ionization to form allylic cations that engage in cyclization reactions to form dihydropyran products. The reactions give the 2,6-trans-stereoisomer as the major products as a result of minimizing steric interactions in a boat-like transition state. The results of these studies are consistent with cationic intermediates, with an intriguing observation of stereochemical retention in one example." @default.
- W3111662104 created "2020-12-21" @default.
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- W3111662104 date "2020-12-09" @default.
- W3111662104 modified "2023-09-27" @default.
- W3111662104 title "Dehydrative Re<sub>2</sub>O<sub>7</sub>-Catalyzed Approach to Dihydropyran Synthesis" @default.
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- W3111662104 doi "https://doi.org/10.1021/acs.orglett.0c03526" @default.
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