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- W3111935731 endingPage "129334" @default.
- W3111935731 startingPage "129334" @default.
- W3111935731 abstract "Synthetic manganese porphyrins (MnPs), in the presence of oxidants, were employed for the degradation of fluoroquinolone antibiotics. Ciprofloxacin (CIP) and levofloxacin (LEV) degradation by iodosylbenzene, iodobenzene diacetate, H2O2 and meta-chloroperbenzoic acid using water-soluble MnP catalysts yielded thirteen and nine products, respectively, seven of which have been proposed for the first time. The MnP catalysts have demonstrated the ability to degrade these antibiotics to a high degree (up to 100% degradation). The structures of the degradation products were proposed based on mass spectrometry analysis, and density functional theory calculations could confirm how the substituent moieties attached to the basic chemical structure of the fluoroquinolones influence the degradation reactions. CIP has been shown to be a more reactive substrate towards the porphyrinic catalysts tested because of its three-membered ring. However, the catalysts could almost completely degrade LEV, highlighting the ability of these porphyrins to act as catalysts to degrade environmental pollutants." @default.
- W3111935731 created "2020-12-21" @default.
- W3111935731 creator A5012873341 @default.
- W3111935731 creator A5030758738 @default.
- W3111935731 creator A5051091339 @default.
- W3111935731 creator A5054719591 @default.
- W3111935731 creator A5057652078 @default.
- W3111935731 date "2021-04-01" @default.
- W3111935731 modified "2023-10-18" @default.
- W3111935731 title "Water-soluble manganese porphyrins as good catalysts for cipro- and levofloxacin degradation: Solvent effect, degradation products and DFT insights" @default.
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- W3111935731 doi "https://doi.org/10.1016/j.chemosphere.2020.129334" @default.
- W3111935731 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33360938" @default.
- W3111935731 hasPublicationYear "2021" @default.
- W3111935731 type Work @default.