FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3111984308> ?p ?o ?g. }

• W3111984308 endingPage "15602" @default.
• W3111984308 startingPage "15592" @default.
• W3111984308 abstract "The transformation of a molecularly complex and irregularly shaped lignin into a nanoscale spherical architecture is anticipated to play a pivotal role in the promotion of lignin valorization. From the standpoint of using colloidal lignin particles (CLPs) as building blocks for a diverse range of applications, it has become essential to study their interactions with soluble compounds of varied origin. However, the lack of model films with well-defined surface properties similar to those of CLPs has hindered fundamental studies using surface-sensitive techniques. Here, we report well-defined and stable thin films prepared from CLPs and demonstrate their suitability for investigation of surface phenomena. Direct adsorption on substrates coated with a cationic anchoring polymer resulted in uniform distribution of CLPs as shown with atomic force microscopy (AFM). Quartz crystal microbalance with dissipation monitoring (QCM-D) experiments revealed higher adsorbed mass of cationic lignin onto the CLP-coated substrate in comparison to the film prepared from dissolved lignin, suggesting preferential adsorption via the carboxylic acid enriched surfaces of CLPs. QCM-D further enabled detection of small changes such as particle swelling or partial dissolution not detectable via bulk methods such as light scattering. The CLP thin films remained stable until pH 8 and displayed only a low degree of swelling. Increasing the pH to 10 led to some instability, but their spherical geometry remained intact until complete dissolution was observed at pH 12. Particles prepared from aqueous acetone or aqueous tetrahydrofuran solution followed similar trends regarding adsorption, pH stability, and wetting, although the particle size affected the magnitude of adsorption. Overall, our results present a practical way to prepare well-defined CLP thin films that will be useful not only for fundamental studies but also as a platform for testing stability and interactions of lignin nanoparticles with materials of technical and biomedical relevance." @default.
• W3111984308 created "2020-12-21" @default.
• W3111984308 creator A5028421299 @default.
• W3111984308 creator A5048393294 @default.
• W3111984308 creator A5067262074 @default.
• W3111984308 creator A5070408418 @default.
• W3111984308 creator A5073131754 @default.
• W3111984308 creator A5078625015 @default.
• W3111984308 date "2020-12-16" @default.
• W3111984308 modified "2023-10-11" @default.
• W3111984308 title "Well-Defined Lignin Model Films from Colloidal Lignin Particles" @default.
• W3111984308 cites W1503715958 @default.
• W3111984308 cites W1970004609 @default.
• W3111984308 cites W1970025468 @default.
• W3111984308 cites W1975943769 @default.
• W3111984308 cites W1986149655 @default.
• W3111984308 cites W1988278858 @default.
• W3111984308 cites W2001727482 @default.
• W3111984308 cites W2005172316 @default.
• W3111984308 cites W2006163208 @default.
• W3111984308 cites W2019749039 @default.
• W3111984308 cites W2023659613 @default.
• W3111984308 cites W2033908451 @default.
• W3111984308 cites W2039434763 @default.
• W3111984308 cites W2053820913 @default.
• W3111984308 cites W2063893319 @default.
• W3111984308 cites W2065280396 @default.
• W3111984308 cites W2065533817 @default.
• W3111984308 cites W2072626380 @default.
• W3111984308 cites W2103086903 @default.
• W3111984308 cites W2115388907 @default.
• W3111984308 cites W2115584603 @default.
• W3111984308 cites W2126838793 @default.
• W3111984308 cites W2133059825 @default.
• W3111984308 cites W2159620031 @default.
• W3111984308 cites W2169294118 @default.
• W3111984308 cites W2410287560 @default.
• W3111984308 cites W2415046430 @default.
• W3111984308 cites W2557458475 @default.
• W3111984308 cites W2593891317 @default.
• W3111984308 cites W2599199563 @default.
• W3111984308 cites W2736992928 @default.
• W3111984308 cites W2737373711 @default.
• W3111984308 cites W2739023495 @default.
• W3111984308 cites W2767977880 @default.
• W3111984308 cites W2772522881 @default.
• W3111984308 cites W2804824261 @default.
• W3111984308 cites W2806065742 @default.
• W3111984308 cites W2887408513 @default.
• W3111984308 cites W2907144111 @default.
• W3111984308 cites W2925112220 @default.
• W3111984308 cites W2944456323 @default.
• W3111984308 cites W2944607417 @default.
• W3111984308 cites W2946408120 @default.
• W3111984308 cites W2976985953 @default.
• W3111984308 cites W2991763618 @default.
• W3111984308 cites W2998764849 @default.
• W3111984308 cites W3008465725 @default.
• W3111984308 cites W3015276089 @default.
• W3111984308 cites W3032905850 @default.
• W3111984308 cites W3036331713 @default.
• W3111984308 doi "https://doi.org/10.1021/acs.langmuir.0c02970" @default.
• W3111984308 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33326249" @default.
• W3111984308 hasPublicationYear "2020" @default.
• W3111984308 type Work @default.
• W3111984308 sameAs 3111984308 @default.
• W3111984308 citedByCount "23" @default.
• W3111984308 countsByYear W31119843082021 @default.
• W3111984308 countsByYear W31119843082022 @default.
• W3111984308 countsByYear W31119843082023 @default.
• W3111984308 crossrefType "journal-article" @default.
• W3111984308 hasAuthorship W3111984308A5028421299 @default.
• W3111984308 hasAuthorship W3111984308A5048393294 @default.
• W3111984308 hasAuthorship W3111984308A5067262074 @default.
• W3111984308 hasAuthorship W3111984308A5070408418 @default.
• W3111984308 hasAuthorship W3111984308A5073131754 @default.
• W3111984308 hasAuthorship W3111984308A5078625015 @default.
• W3111984308 hasConcept C111368507 @default.
• W3111984308 hasConcept C127313418 @default.
• W3111984308 hasConcept C127413603 @default.
• W3111984308 hasConcept C134514944 @default.
• W3111984308 hasConcept C150394285 @default.
• W3111984308 hasConcept C178790620 @default.
• W3111984308 hasConcept C183882617 @default.
• W3111984308 hasConcept C184651966 @default.
• W3111984308 hasConcept C185592680 @default.
• W3111984308 hasConcept C192562407 @default.
• W3111984308 hasConcept C2778517922 @default.
• W3111984308 hasConcept C2781052789 @default.
• W3111984308 hasConcept C42360764 @default.
• W3111984308 hasConcept C521977710 @default.
• W3111984308 hasConcept C59789625 @default.
• W3111984308 hasConcept C88380143 @default.
• W3111984308 hasConcept C9996572 @default.
• W3111984308 hasConceptScore W3111984308C111368507 @default.
• W3111984308 hasConceptScore W3111984308C127313418 @default.
• W3111984308 hasConceptScore W3111984308C127413603 @default.
• W3111984308 hasConceptScore W3111984308C134514944 @default.

• next