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- W3112205063 abstract "Phosphorus promoted HZSM-5 zeolites (P-HZSM-5) were prepared by synthetic methods of incipient wetness impregnation and in situ synthesis, respectively. This was characterized by the means of powder X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller method (BET), thermogravimetry (TG), and NH 3 -TPD. The P-HZSM-5 zeolite prepared by incipient wetness impregnation has a large specific surface area and pore size, and the weak acidity is remarkably increased. The catalytic activity of P-HZSM-5 for the coupling transformation of methanol with 1-butene to propylene was investigated. Under the reaction conditions of temperature at 550 °C, pressure at 0.4 MPa, space velocity at 1800 mL/(g cat h), and mole ratio of CH 3 OH/C 4 H 8 at 1:1, the conversion of C 4 H 8 can reach to 75.8%, and the selectivity and yield of propylene are 42.2% and 31.9%, respectively." @default.
- W3112205063 created "2020-12-21" @default.
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- W3112205063 date "2021-05-01" @default.
- W3112205063 modified "2023-09-27" @default.
- W3112205063 title "Phosphorus promoted HZSM-5 zeolites for the coupling transformation of methanol with 1-butene to propylene" @default.
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- W3112205063 doi "https://doi.org/10.1139/cjc-2020-0316" @default.
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