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• W3112778812 endingPage "013601" @default.
• W3112778812 startingPage "013601" @default.
• W3112778812 abstract "Prussian blue analogues (PBAs) are nanoporous materials that consist of a cyano-bridged three-dimensional (3D) metal framework, i.e., –M–NC–Fe–CN–M– (M = Cr, Mn, Fe, Co, Ni, Cu, and Cd), and a guest alkali metal and H2O. Among the various PBAs, a Cd compound has a large framework with a side of ∼5.4 Å. We found that Na1.96Cd[Fe(CN)6]0.99 shows a phase transition from a cubic ((Fmbar{3}m); Z = 4) to a monoclinic (I12/m1; Z = 2) structure at 400 K with a decrease in temperature. During the cubic phase, Na+ is located at the octahedral (48g) site. Based on structural analysis, we ascribed the transition into a monoclinic phase to the Na ordering at the stable site among the octahedral sites." @default.
• W3112778812 created "2020-12-21" @default.
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• W3112778812 date "2021-01-15" @default.
• W3112778812 modified "2023-10-16" @default.
• W3112778812 title "Structural Phase Transition Triggered by Na Ordering in Na_1.96Cd[Fe(CN)₆]_0.99" @default.
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• W3112778812 doi "https://doi.org/10.7566/jpsj.90.013601" @default.
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