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- W3113017722 abstract "In this study, a graphite rotating disc electrode was successfully designed and applied to conduct electrochemical measurements under flow conditions in molten LiCl-KCl at 773 K. The concentration and diffusion coefficients of Eu 3+ and Eu 2+ in molten salt were quantitatively measured with this electrode by applying in situ cyclic voltammetry and chronoamperometry techniques. The initial concentration ratio of Eu 3+ /Eu 2+ in LiCl-KCl-0.5 wt% EuCl 3 was calculated to be 2.37. The calculated diffusion coefficients of Eu 3+ and Eu 2+ in the salt were 9.31 ± 0.06 × 10 −5 cm 2 s −1 and 9.65 ± 0.6 × 10 −5 cm 2 s −1 , respectively. A decrease of the diffusion coefficient of Eu 3+ and Eu 2+ was observed at a higher concentration of EuCl 3 , which implies the enhanced Eu-Eu ion interaction. This electrode design is expected to be utilized for the concentration measurement of multivalent ions in a flowing molten salt." @default.
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- W3113017722 date "2020-12-01" @default.
- W3113017722 modified "2023-10-18" @default.
- W3113017722 title "In Situ Electrochemical Study of the Coexistence of Eu<sup>3+</sup> and Eu<sup>2+</sup> in Molten LiCl-KCl by Rotating Disc Electrode" @default.
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- W3113017722 doi "https://doi.org/10.1149/1945-7111/abd2da" @default.
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