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• W3113089155 abstract "A novel copper-catalyzed intermolecular aminoalkynylation of alkenes through a radical relay process has been developed in this work, in which N-fluoro-N-alkylsulfonamides (NFASs) are used as nitrogen-centered radical precursors and alkynyltrimethoxysilanes as alkynylating reagents. This method presents an efficient and straightforward approach to various enantioenriched 2-alkynyl-2-arylethylamines in good yields with excellent enantioselectivity, and these products can be readily converted into a series of synthetically useful chiral terminal alkynes, allenes, alkenes, amines, amino acids, and N-heterocycles." @default.
• W3113089155 created "2020-12-21" @default.
• W3113089155 creator A5001573477 @default.
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• W3113089155 date "2020-12-16" @default.
• W3113089155 modified "2023-10-17" @default.
• W3113089155 title "Enantioselective Intermolecular Aminoalkynylation of Styrenes via Copper-Catalyzed Radical Relay" @default.
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• W3113089155 doi "https://doi.org/10.1021/acs.orglett.0c03826" @default.
• W3113089155 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33325721" @default.
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