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- W3113120063 abstract "• This strategy make the combination of privileged isoxazole and spirooxindole. • Medicinally important 3′-(nitroisoxazol)spiro[pyrrolidin-3,2′-oxindoles] containing trifluoromethyl were constructed. • The corresponding products were afforded in good to high yields (76–93%) and excellent diastereoselectivities (>20:1). • The atom-economic 1,3-dipolar cycloaddition reaction was applied in this method. The highly diastereoselective 1,3-dipolar cycloaddition reaction of N -2,2,2-trifluoroethyl-substituted isatin imines with styrylisoxazoles was developed for the synthesis of a wide range of isoxazole- and trifluoromethyl-containing spiro[pyrrolidin-oxindoles] in high yields with excellent diastereoselectivities. Further transformations of the final products and the gram-scale capacity of this method were also assessed." @default.
- W3113120063 created "2020-12-21" @default.
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- W3113120063 date "2021-01-01" @default.
- W3113120063 modified "2023-10-17" @default.
- W3113120063 title "Highly diastereoselective assembly of isoxazole and trifluoromethyl containing spiro[pyrrolidin-oxindoles] from N-2,2,2-trifluoroethyl-substituted isatin imines and styrylisoxazoles" @default.
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- W3113120063 doi "https://doi.org/10.1016/j.tetlet.2020.152687" @default.
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