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- W3113280014 abstract "Precatalyst control: [CuII(OTf)2(pyb)2]2 CH3CN (1), in which pyb is 1-(2-pyridyl)benzotriazole, enables the synthesis of a wide range of propargylamines by the A3 coupling reaction at room temperature in the absence of additives. The hybrid N,N′-bidentate pyb ligand imposes exclusive trans coordination at Cu, can rotate and modulate charge distribution and flux, thus orchestrating structural and electronic precatalyst control permitting activation of the C−H bond." @default.
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- W3113280014 date "2021-01-26" @default.
- W3113280014 modified "2023-10-14" @default.
- W3113280014 title "Structural and Electronic Control of the Bidentate 1‐(2‐pyridyl)benzotriazole Ligand in Copper Chemistry with Application to Catalysis in the A <sup>3</sup> Coupling Reaction" @default.
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- W3113280014 doi "https://doi.org/10.1002/chem.202004781" @default.
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