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- W3113707623 abstract "The classic version of aza-Wittig reactions, namely, reactions between phosphazenes and compounds with polar double bonds, is widely employed in organic synthesis to produce C=N bonds. However, only a limited number of aza-Wittig reactions between phosphazenes and compounds with triple bonds is known, which has a lot to do with certain structural features of the reactants, wherein additional activation is required. This review provides a guide to those rare examples of aza-Wittig reactions with acetylenes and nitriles. A unique trait of these atom-economic processes is that they afford Wittig or new aza-Wittig reagents, respectively, which offers new opportunities for employing these reactions in organic syntheses, especially those of N-heterocyclic compounds." @default.
- W3113707623 created "2021-01-05" @default.
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- W3113707623 date "2020-11-01" @default.
- W3113707623 modified "2023-09-26" @default.
- W3113707623 title "Acetylenes and nitriles as unconventional reactants for aza-Wittig reactions" @default.
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- W3113707623 doi "https://doi.org/10.1016/j.mencom.2020.11.001" @default.
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