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- W3113993013 abstract "Novel mononuclear metal complexes with the formula (M=Pd (1); M=Pt (2)) were obtained when N,N'-bis[2'-(diphenylphosphino)phenyl]propane-1,3-diamine, I was mixed with cisdichlorobis(diethylsulfide)palladium and platinum in the presence of NEt3. Two mononuclear metal compounds with the fomula [M(Ph2PC6H4NH)(SEt2)Cl] (M=Pd (3); M=Pt (4)) were synthesized from and N-(2'-diphenylphosphinophenyl)-4-amino-1,1,1,5,5, 5-hexafluoro-3-penten-2-one, II by the elimination reaction of hexafluoro pentenone. The X-ray single crystal structures of 1 and 4 are described. X-ray single crystal diffraction analyses reveal that compound 1 is a mononuclear palladium compound with P,N,N,P-coordination mode and 4 is a mononuclear platinum compound with P,N-coordination mode." @default.
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- W3113993013 date "1998-01-01" @default.
- W3113993013 modified "2023-09-25" @default.
- W3113993013 title "Synthesis and Characterization of Palladium and Platinum Complexes of N,N'-Bis[2'-(diphenylphosphino)phenyl]propane-1,3-diamine. Single-Crystal Structures of $[Pd(Ph_2PC_6H_4NC_3H_6NC_6H_4PPh_2)]$ and $[Pt(Ph_2PC_6H_4NH)(SEt_2)Cl]$" @default.
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