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- W3114022012 abstract "具有烧绿石结构的Cd2Ru2O7在形成长程反铁磁序的同时进入反常的金属态.采用高压高温方法制备了一系列Pb掺杂的Cd2-xPbxRu2O7（0 x 2）多晶样品，并系统研究了其晶体结构和电阻率、磁化率、热电势等物理性质.尽管Pb2Ru2O7是泡利顺磁金属，但少量Pb2+掺杂的样品Cd1.8Pb0.2Ru2O7却呈现出明显的金属-绝缘体转变，与施加静水压和少量Ca2+掺杂的效果类似.通过与类似的烧绿石Ru5+氧化物进行对比，提出Cd2Ru2O7中的Ru5+-4d3电子态恰好处于巡游到局域过渡的区域，少量Pb2+掺杂造成的晶格无序增强了电子的局域性，使得形成反铁磁序的同时伴随出现了金属-绝缘体转变.这表明具有烧绿石结构的Ru5+氧化物是研究巡游-局域电子转变的理想材料体系." @default.
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- W3114022012 date "2018-01-01" @default.
- W3114022012 modified "2023-10-17" @default.
- W3114022012 title "Effect of Pb doping on metallic state of cubic pyrochlore Cd2Ru2O7" @default.
- W3114022012 doi "https://doi.org/10.7498/aps.67.20180343" @default.
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