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- W3114333603 abstract "Abstract The densities of several liquid lanthanoid sesquioxides (Ln 2 O 3 , Ln = Er, Ho, Tb, Gd) were measured over the temperature range from 2700 K (the approximate melting point of these materials) to 3200 K. These measurements were performed using the Electrostatic Levitation Furnace onboard the International Space Station (ISS‐ELF). Based on the Coulomb force between the charged samples and surrounding electrodes and employing a rapid feedback control process, specimens were stably levitated and subsequently melted by high power lasers. The molten oxides exhibited spherical morphologies and their volumes were readily calculated from magnified images. Subsequent weighing of the samples on Earth allowed the densities of the oxides to be determined. The densities of Er 2 O 3 , Ho 2 O 3 , Tb 2 O 3 , and Gd 2 O 3 at their melting temperatures ( T m ) were found to be 8170, 8035, 7451, and 7268 kg/m 3 , respectively, and these density values were shown to exhibit a linear correlation with temperature. The molar volumes of these oxides at their T m values were calculated and compared with those of other sesquioxides (Al 2 O 3 , Ga 2 O 3 , and B 2 O 3 ). The molar volumes of the nonglass‐forming sesquioxides (Er 2 O 3 , Ho 2 O 3 , Tb 2 O 3 , Gd 2 O 3 , Al 2 O 3 , and Ga 2 O 3 ) showed linear correlations with the cubes of their cation radii, whereas those of the glass‐forming oxide (B 2 O 3 , As 2 O 3 , and Sb 2 O 3 ) showed different correlations." @default.
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- W3114333603 date "2021-02-09" @default.
- W3114333603 modified "2023-10-14" @default.
- W3114333603 title "Densities of liquid lanthanoid sesquioxides measured with the electrostatic levitation furnace in the ISS" @default.
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- W3114333603 doi "https://doi.org/10.1111/jace.17674" @default.
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