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- W3114667684 abstract "A generally useful Ni(II)/trisoxazoline-catalyzed asymmetric sulfa-Michael/Aldol cascade reaction is introduced to access chiral 3-amine-tetrahydrothiophene derivatives containing a quaternary stereocenter (32 examples, up to 93% yield, > 20:1 dr and 92% ee). Moreover, the novel strategy offers an efficient and convenient approach to construct chiral thionucleoside analogues." @default.
- W3114667684 created "2021-01-05" @default.
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- W3114667684 date "2020-12-17" @default.
- W3114667684 modified "2023-09-24" @default.
- W3114667684 title "Asymmetric Synthesis of 3-Amine-tetrahydrothiophenes with a Quaternary Stereocenter via Nickel(II)/Trisoxazoline-Catalyzed Sulfa-Michael/Aldol Cascade Reaction: Divergent Access to Chiral Thionucleosides" @default.
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- W3114667684 doi "https://doi.org/10.1021/acs.orglett.0c03747" @default.
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