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- W3115405536 abstract "Abstract This short review presents an overview of visible-light-driven asymmetric catalysis by chiral complexes of first-row transition metals. The processes described here include dual catalysis by a chiral complex of copper, nickel, cobalt, or chromium and an additional photoredox or energy-transfer catalyst, and bifunctional catalysis by a single chiral copper or nickel catalyst. These methods allow valuable transformations with high functional group compatibility. They provide stereoselective construction of carbon–carbon or carbon–heteroatom bonds under mild conditions, and produce a diverse range of previously unknown enantioenriched compounds. 1 Introduction 2 Nickel-Based Photocatalytic Asymmetric Catalysis 3 Copper-Based Photocatalytic Asymmetric Catalysis 4 Photocatalytic Asymmetric Catalysis by Chiral Complexes of Cobalt or Chromium 5 Conclusion" @default.
- W3115405536 created "2021-01-05" @default.
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- W3115405536 date "2020-12-30" @default.
- W3115405536 modified "2023-10-03" @default.
- W3115405536 title "Visible-Light-Promoted Asymmetric Catalysis by Chiral Complexes of First-Row Transition Metals" @default.
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- W3115405536 doi "https://doi.org/10.1055/a-1344-2473" @default.
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