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• W3115481878 abstract "We report on the new monosubstituted aluminum Keggin-type germanotungstate (C4H12N)4[HAlGeW11O39(H2O)]·11H2O ([Al(H2O)GeW11]4-), which has been synthesized at room temperature via rearrangement of the dilacunary [γ-GeW10O36]8- polyoxometalate precursor. [Al(H2O)GeW11]4- has been characterized thoroughly both in the solid state by single-crystal and powder X-ray diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis as well as in solution by cyclic voltammetry (CV) 183W, 27Al NMR and UV-vis spectroscopy. A study on the antibacterial properties of [Al(H2O)GeW11]4- and the known aluminum(III)-centered Keggin polyoxotungstates (Al-POTs) α-Na5[AlW12O40] (α-[AlW12O40]5-) and Na6[Al(AlOH2)W11O39] ([Al(AlOH2)W11O39]6-) revealed enhanced activity for all three Al-POTs against the Gram-negative bacterium Moraxella catarrhalis (minimum inhibitory concentration (MIC) up to 4 μg mL-1) and the Gram-positive Enterococcus faecalis (MIC up to 128 μg mL-1) compared to the inactive Al(NO3)3 salt (MIC > 256 μg mL-1). CV indicates the redox activity of the Al-POTs as a dominating factor for the observed antibacterial activity with increased tendency to reduction, resulting in increased antibacterial activity of the POT." @default.
• W3115481878 created "2021-01-05" @default.
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• W3115481878 date "2020-12-17" @default.
• W3115481878 modified "2023-10-16" @default.
• W3115481878 title "Aluminum-Substituted Keggin Germanotungstate [HAl(H₂O)GeW₁₁O₃₉]^4–: Synthesis, Characterization, and Antibacterial Activity" @default.
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• W3115481878 doi "https://doi.org/10.1021/acs.inorgchem.0c03311" @default.
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• W3115481878 hasPublicationYear "2020" @default.
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