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- W3116362287 abstract "Adjusting the surface structures and electronic structures of metal nanocrystals (NCs) by the metal-organic interface interaction is an emerging strategy to enhance their electrocatalytic behavior. In this work, the d-phenylalanine-functionalized graphene (DPHE-GS) anchoring Pd NCs (denoted as Pd/DPHE-GS) was fabricated via the diazo-reaction followed by a simple chemical reduction. Owing to the metal-organic interface interaction between Pd NCs and DPHE, the size, distribution and electronic structures of Pd NCs on the surface of DPHE-GS can be adjusted. Therefore, the Pd/DPHE-GS shows the highest electrocatalytic activity and the most robust long-term durability and stability towards methanol and ethanol oxidation reaction (MOR and EOR) compared to the commercial Pd/C and other counterparts. This work presents an effective interface engineering strategy to enhance electrocatalytic property." @default.
- W3116362287 created "2021-01-05" @default.
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- W3116362287 date "2021-04-01" @default.
- W3116362287 modified "2023-10-17" @default.
- W3116362287 title "Metal-organic interface engineering for coupling palladium nanocrystals over functionalized graphene as an advanced electrocatalyst of methanol and ethanol oxidation" @default.
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- W3116362287 doi "https://doi.org/10.1016/j.jcis.2020.12.080" @default.
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