FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3116995963> ?p ?o ?g. }

• W3116995963 endingPage "116406" @default.
• W3116995963 startingPage "116406" @default.
• W3116995963 abstract "As an emerging brominated flame retardant (BFR), tetrabromobisphenol S (TBBPS) has been frequently detected in the environmental media and organisms. Knowledges on the transformation and fate of TBBPS in both environment and engineering systems are essential to its ecological risk assessment. Herein, we reported the photochemical decomposition of TBBPS in aqueous solution upon 254 nm ultraviolet irradiation (UV254). Results show that TBBPS was highly photoreactive, most likely due to the presence of four ortho-bromine substituents. The molar absorption coefficient and quantum yield of TBBPS were found to be pH-dependent, with the monoanionic form being most photoreactive. A series of photoproducts were identified by solid phase extraction (SPE) combined with liquid chromatography-electrospray ionization-triple quadrupole mass spectrometry (LC-ESI(+)-MS/MS. The photolysis of TBBPS likely proceeded through photonucleophilic substitution, photoreductive debromination, and β-scission reactions. A ketocarbene, possibly derived from the lower lying excited triplet state, was proposed to be involved in the photolysis of TBBPS. Ion chromatography analysis revealed that debromination occurred quickly, and the yield of bromide (Br−) approached 100% after 90 min irradiation. The presence of SRNOM and MRNOM inhibited the photodegradation rate of TBBPS, which is likely due to the light-screening and physical quenching effects of natural organic matter (NOM). Our results reveal that photolysis is an important process for the attenuation of TBBPS in aquatic system; however, naturally occurring species such as NOM can appreciably retard the decay of TBBPS." @default.
• W3116995963 created "2021-01-05" @default.
• W3116995963 creator A5027474848 @default.
• W3116995963 creator A5036145347 @default.
• W3116995963 creator A5067880508 @default.
• W3116995963 creator A5072864768 @default.
• W3116995963 creator A5076008164 @default.
• W3116995963 creator A5076301183 @default.
• W3116995963 creator A5076418678 @default.
• W3116995963 date "2021-02-01" @default.
• W3116995963 modified "2023-10-17" @default.
• W3116995963 title "Aqueous photodecomposition of the emerging brominated flame retardant tetrabromobisphenol S (TBBPS)" @default.
• W3116995963 cites W1963688170 @default.
• W3116995963 cites W1966139208 @default.
• W3116995963 cites W1984305883 @default.
• W3116995963 cites W1990048957 @default.
• W3116995963 cites W1995899727 @default.
• W3116995963 cites W2001358468 @default.
• W3116995963 cites W2004779786 @default.
• W3116995963 cites W2007614109 @default.
• W3116995963 cites W2009576855 @default.
• W3116995963 cites W2023563114 @default.
• W3116995963 cites W2034599618 @default.
• W3116995963 cites W2035609073 @default.
• W3116995963 cites W2040840905 @default.
• W3116995963 cites W2046711286 @default.
• W3116995963 cites W2047877887 @default.
• W3116995963 cites W2058779425 @default.
• W3116995963 cites W2071759548 @default.
• W3116995963 cites W2075747862 @default.
• W3116995963 cites W2078536057 @default.
• W3116995963 cites W2080985187 @default.
• W3116995963 cites W2083292878 @default.
• W3116995963 cites W2086577260 @default.
• W3116995963 cites W2106012378 @default.
• W3116995963 cites W2108632238 @default.
• W3116995963 cites W2114021596 @default.
• W3116995963 cites W2162216076 @default.
• W3116995963 cites W2177396565 @default.
• W3116995963 cites W2262930414 @default.
• W3116995963 cites W2314019764 @default.
• W3116995963 cites W2315589562 @default.
• W3116995963 cites W2338186405 @default.
• W3116995963 cites W2465873823 @default.
• W3116995963 cites W2490108010 @default.
• W3116995963 cites W2529957433 @default.
• W3116995963 cites W2531488260 @default.
• W3116995963 cites W2754975536 @default.
• W3116995963 cites W2766989485 @default.
• W3116995963 cites W2796672445 @default.
• W3116995963 cites W2801037897 @default.
• W3116995963 cites W2885691033 @default.
• W3116995963 cites W2893659216 @default.
• W3116995963 cites W2996286278 @default.
• W3116995963 cites W3005577592 @default.
• W3116995963 cites W3008703103 @default.
• W3116995963 doi "https://doi.org/10.1016/j.envpol.2020.116406" @default.
• W3116995963 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33412445" @default.
• W3116995963 hasPublicationYear "2021" @default.
• W3116995963 type Work @default.
• W3116995963 sameAs 3116995963 @default.
• W3116995963 citedByCount "12" @default.
• W3116995963 countsByYear W31169959632021 @default.
• W3116995963 countsByYear W31169959632022 @default.
• W3116995963 countsByYear W31169959632023 @default.
• W3116995963 crossrefType "journal-article" @default.
• W3116995963 hasAuthorship W3116995963A5027474848 @default.
• W3116995963 hasAuthorship W3116995963A5036145347 @default.
• W3116995963 hasAuthorship W3116995963A5067880508 @default.
• W3116995963 hasAuthorship W3116995963A5072864768 @default.
• W3116995963 hasAuthorship W3116995963A5076008164 @default.
• W3116995963 hasAuthorship W3116995963A5076301183 @default.
• W3116995963 hasAuthorship W3116995963A5076418678 @default.
• W3116995963 hasConcept C121332964 @default.
• W3116995963 hasConcept C161790260 @default.
• W3116995963 hasConcept C162356407 @default.
• W3116995963 hasConcept C162847780 @default.
• W3116995963 hasConcept C171001562 @default.
• W3116995963 hasConcept C178790620 @default.
• W3116995963 hasConcept C184651966 @default.
• W3116995963 hasConcept C185592680 @default.
• W3116995963 hasConcept C205474432 @default.
• W3116995963 hasConcept C2780260993 @default.
• W3116995963 hasConcept C2780287514 @default.
• W3116995963 hasConcept C40684141 @default.
• W3116995963 hasConcept C43617362 @default.
• W3116995963 hasConcept C517835270 @default.
• W3116995963 hasConcept C54582936 @default.
• W3116995963 hasConcept C62520636 @default.
• W3116995963 hasConcept C65165184 @default.
• W3116995963 hasConcept C75473681 @default.
• W3116995963 hasConcept C91881484 @default.
• W3116995963 hasConceptScore W3116995963C121332964 @default.
• W3116995963 hasConceptScore W3116995963C161790260 @default.
• W3116995963 hasConceptScore W3116995963C162356407 @default.
• W3116995963 hasConceptScore W3116995963C162847780 @default.
• W3116995963 hasConceptScore W3116995963C171001562 @default.
• W3116995963 hasConceptScore W3116995963C178790620 @default.

• next