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• W3117007094 endingPage "9251" @default.
• W3117007094 startingPage "9239" @default.
• W3117007094 abstract "Simple n-alcohols, such as 1-dodecanol, show anomalous film-forming and friction behaviors under elastohydrodynamic lubrication (EHL) conditions, as found inside bearings and gears. Using tribometer, diamond anvil cell (DAC), and differential scanning calorimetry (DSC) experiments, we show that liquid 1-dodecanol undergoes a pressure-induced solidification when entrained into EHL contacts. Different solid polymorphs are formed inside the contact depending on the temperature and pressure conditions. Surprisingly, at a moderate temperature and pressure, 1-dodecanol forms a polymorph that exhibits robust macroscale superlubricity. The DAC and DSC experiments show that superlubricity is facilitated by the formation of lamellar, hydrogen-bonded structures of hexagonally close-packed molecules, which promote interlayer sliding. This novel superlubricity mechanism is similar to that proposed for the two-dimensional materials commonly employed as solid lubricants, but it also enables the practical advantages of liquid lubricants to be maintained. When the pressure is increased, 1-dodecanol undergoes a polymorphic transformation into a phase that gives a higher friction. The DAC and DSC experiments indicate that the high-friction polymorph is an orthorhombic crystal. The polymorphic transformation pressure coincides with the onset of a dimple formation in the EHL films, revealing that the anomalous film shapes are caused by the formation of rigid orthorhombic crystals inside the contact. This is the first demonstration of a macroscale superlubricity in an EHL contact lubricated by a nonaqueous liquid that arises from bulk effects rather than tribochemical transformations at the surfaces. Since the superlubricity observed here results from phase transformations, it is continuously self-replenishing and is insensitive to surface chemistry and topology. This discovery creates the possibility of implementing superlubricity in a wide range of machine components, which would result in enormous improvements in efficiency and durability." @default.
• W3117007094 created "2021-01-05" @default.
• W3117007094 creator A5012777027 @default.
• W3117007094 creator A5021277983 @default.
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• W3117007094 creator A5035480573 @default.
• W3117007094 creator A5061415778 @default.
• W3117007094 creator A5064945661 @default.
• W3117007094 date "2021-02-10" @default.
• W3117007094 modified "2023-09-23" @default.
• W3117007094 title "Macroscale Superlubricity and Polymorphism of Long-Chain <i>n</i>-Alcohols" @default.
• W3117007094 cites W1798922910 @default.
• W3117007094 cites W1965915393 @default.
• W3117007094 cites W1969406823 @default.
• W3117007094 cites W1971630281 @default.
• W3117007094 cites W1972893278 @default.
• W3117007094 cites W1974986272 @default.
• W3117007094 cites W1975320306 @default.
• W3117007094 cites W1977674282 @default.
• W3117007094 cites W1978308767 @default.
• W3117007094 cites W1979838577 @default.
• W3117007094 cites W1981972983 @default.
• W3117007094 cites W1983197658 @default.
• W3117007094 cites W1984576596 @default.
• W3117007094 cites W1988005274 @default.
• W3117007094 cites W1990704251 @default.
• W3117007094 cites W1992456731 @default.
• W3117007094 cites W1992979721 @default.
• W3117007094 cites W1997126459 @default.
• W3117007094 cites W1997867909 @default.
• W3117007094 cites W1998657460 @default.
• W3117007094 cites W2003516331 @default.
• W3117007094 cites W2008936843 @default.
• W3117007094 cites W2009025170 @default.
• W3117007094 cites W2010115387 @default.
• W3117007094 cites W2010283975 @default.
• W3117007094 cites W2010504513 @default.
• W3117007094 cites W2010627938 @default.
• W3117007094 cites W2017160472 @default.
• W3117007094 cites W2018964489 @default.
• W3117007094 cites W2020851838 @default.
• W3117007094 cites W2023836688 @default.
• W3117007094 cites W2027456354 @default.
• W3117007094 cites W2029078765 @default.
• W3117007094 cites W2029661939 @default.
• W3117007094 cites W2030141326 @default.
• W3117007094 cites W2033295202 @default.
• W3117007094 cites W2033473063 @default.
• W3117007094 cites W2037093839 @default.
• W3117007094 cites W2039800648 @default.
• W3117007094 cites W2048613675 @default.
• W3117007094 cites W2049572489 @default.
• W3117007094 cites W2050313757 @default.
• W3117007094 cites W2050827072 @default.
• W3117007094 cites W2051777498 @default.
• W3117007094 cites W2054826816 @default.
• W3117007094 cites W2055654706 @default.
• W3117007094 cites W2057665474 @default.
• W3117007094 cites W2063983145 @default.
• W3117007094 cites W2067984862 @default.
• W3117007094 cites W2081788120 @default.
• W3117007094 cites W2082712136 @default.
• W3117007094 cites W2088667178 @default.
• W3117007094 cites W2089668915 @default.
• W3117007094 cites W2092681283 @default.
• W3117007094 cites W2096440055 @default.
• W3117007094 cites W2101493184 @default.
• W3117007094 cites W2109689609 @default.
• W3117007094 cites W2110916489 @default.
• W3117007094 cites W2118688907 @default.
• W3117007094 cites W2121703122 @default.
• W3117007094 cites W2122689218 @default.
• W3117007094 cites W2125659143 @default.
• W3117007094 cites W2135146471 @default.
• W3117007094 cites W2144384035 @default.
• W3117007094 cites W2144985182 @default.
• W3117007094 cites W2155356343 @default.
• W3117007094 cites W2168921430 @default.
• W3117007094 cites W2315916784 @default.
• W3117007094 cites W2326004683 @default.
• W3117007094 cites W2416164760 @default.
• W3117007094 cites W2486201738 @default.
• W3117007094 cites W2515162222 @default.
• W3117007094 cites W2529359429 @default.
• W3117007094 cites W2545265651 @default.
• W3117007094 cites W2560438953 @default.
• W3117007094 cites W2605863955 @default.
• W3117007094 cites W2750857672 @default.
• W3117007094 cites W2752118015 @default.
• W3117007094 cites W2795016212 @default.
• W3117007094 cites W2901325622 @default.
• W3117007094 cites W2907780735 @default.
• W3117007094 cites W2912002848 @default.
• W3117007094 cites W2912021500 @default.
• W3117007094 cites W2921060940 @default.
• W3117007094 cites W296518914 @default.
• W3117007094 cites W2991828546 @default.
• W3117007094 cites W2998747964 @default.

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