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- W3117025227 abstract "We report the syntheses of highly dispersed CoNi bimetallic catalysts on the surface of α-MoC based on the strong metal support interaction (SMSI) effect. The interaction between the nearly atomically dispersed Co and Ni atoms was observed for the first time by the real-space chemical mapping at the atomic level. Combined with the ability of α-MoC to split water at low temperatures, the as-synthesized CoNi/α-MoC catalysts exhibited robust and synergistic performance for the hydrogen production from hydrolysis of ammonia borane. The metal-normalized activity of the bimetallic 1.5Co1.5Ni/α-MoC catalyst reached 321.1 molH2·mol-1CoNi·min-1 at 298 K, which surpasses all the noble metal-free catalysts ever reported and is four times higher than that of the commercial Pt/C catalyst." @default.
- W3117025227 created "2021-01-05" @default.
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- W3117025227 date "2020-12-31" @default.
- W3117025227 modified "2023-10-15" @default.
- W3117025227 title "Maximizing the Synergistic Effect of CoNi Catalyst on α-MoC for Robust Hydrogen Production" @default.
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- W3117025227 doi "https://doi.org/10.1021/jacs.0c11285" @default.
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