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- W3117839565 endingPage "129796" @default.
- W3117839565 startingPage "129796" @default.
- W3117839565 abstract "Two new tri- and tetra-nuclear Ni(II)-based complexes, [{NiL(EtOH)(μ-OAc)}2Ni]·4EtOH (1) and [Ni4L2(μ3-OMe)4(MeOH)4] (2), supported by a more flexible salamo-type ligand H2L containing coumarin functional groups have been synthesized. Complex 1 is tri-nuclear, including three Ni(II) atoms with hexa-coordinated octahedral geometries. X-ray single-crystal structure analysis revealed that complex 2 is a novel tetra-nuclear structure previously unreported, and the geometry of four Ni(II) atoms with hexa-coordinate can be regarded as octahedron. Interestingly, due to the improvement of the flexibility of salamo-type ligand H2L, complex 2 is obtained by the form of intramolecular self-assembly. Moreover, the fluorescence properties of H2L and its Ni(II)-based complexes were studied. Subsequently, the supramolecular structure, Hirshfeld surfaces analyses and DFT calculations of the two Ni(II)-based complexes have been performed." @default.
- W3117839565 created "2021-01-05" @default.
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- W3117839565 date "2021-03-01" @default.
- W3117839565 modified "2023-10-17" @default.
- W3117839565 title "An investigation into three-dimensional octahedral multi-nuclear Ni(II)-based complexes supported by a more flexible salamo-type ligand" @default.
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- W3117839565 doi "https://doi.org/10.1016/j.molstruc.2020.129796" @default.
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