Matches in SemOpenAlex for { <https://semopenalex.org/work/W3118173929> ?p ?o ?g. }
- W3118173929 endingPage "1201" @default.
- W3118173929 startingPage "1195" @default.
- W3118173929 abstract "Due to the existence of some cross properties such as SHG (second-harmonic generation), ferroelectricity, piezoelectricity, and thermoelectricity, molecular ferroelectrics have been widely used as a composite multipurpose material. Particularly, organic–inorganic molecular ferroelectrics have received much interest recently because of their unique flexible structures, friendly environment, ease of synthesis, etc. Also, these hybrids show great flexibility in band-gap engineering. Here we report a new molecular halide, [C6H13N3SbBr5]n (1; C6H13N3 = 1-(3-aminopropyl)imidazole), which experiences a unique ferroelectric to paraelectric phase transition at around 230 K from space group P21 to P21/c. Significantly, compound 1 exhibits a narrow band gap with a value of 2.52 eV, large pronounced SHG-active, perfect rectangle hysteresis loops with a large spontaneous polarization of 6.86 μC/cm2. DSC (differential scanning calorimetry) and dielectric dependence on temperature tests and the volume change before and after the phase transition show that compound 1 is characterized by a second-order phase transition. These findings will contribute to the multifunctional materials field of organic–inorganic hybrids." @default.
- W3118173929 created "2021-01-05" @default.
- W3118173929 creator A5004634467 @default.
- W3118173929 creator A5004692450 @default.
- W3118173929 creator A5004810605 @default.
- W3118173929 creator A5010889732 @default.
- W3118173929 creator A5029138822 @default.
- W3118173929 creator A5068209475 @default.
- W3118173929 creator A5073415848 @default.
- W3118173929 creator A5081595730 @default.
- W3118173929 date "2020-12-24" @default.
- W3118173929 modified "2023-10-09" @default.
- W3118173929 title "Coupling Narrow Band Gap and Switchable SHG Responses in a New Molecule Ferroelectric: Imidazolyl Propylamine Pentabromo Stibium(III)" @default.
- W3118173929 cites W2002458174 @default.
- W3118173929 cites W2020052402 @default.
- W3118173929 cites W2073031941 @default.
- W3118173929 cites W2230715130 @default.
- W3118173929 cites W2333297357 @default.
- W3118173929 cites W2334797496 @default.
- W3118173929 cites W2345680776 @default.
- W3118173929 cites W2407518462 @default.
- W3118173929 cites W2411142273 @default.
- W3118173929 cites W2415165064 @default.
- W3118173929 cites W2605866978 @default.
- W3118173929 cites W2606996551 @default.
- W3118173929 cites W2610319613 @default.
- W3118173929 cites W2772443558 @default.
- W3118173929 cites W2785518057 @default.
- W3118173929 cites W2808649396 @default.
- W3118173929 cites W2883861832 @default.
- W3118173929 cites W2899597285 @default.
- W3118173929 cites W2921257713 @default.
- W3118173929 cites W2933052513 @default.
- W3118173929 cites W2943010106 @default.
- W3118173929 cites W2953561788 @default.
- W3118173929 cites W2968822263 @default.
- W3118173929 cites W2972474221 @default.
- W3118173929 cites W2976650944 @default.
- W3118173929 cites W2979957808 @default.
- W3118173929 cites W2993434298 @default.
- W3118173929 cites W2995915363 @default.
- W3118173929 cites W2996065726 @default.
- W3118173929 cites W2999625237 @default.
- W3118173929 cites W2999941216 @default.
- W3118173929 cites W3001645213 @default.
- W3118173929 cites W3004815014 @default.
- W3118173929 cites W3006042629 @default.
- W3118173929 cites W3022364331 @default.
- W3118173929 cites W3032108431 @default.
- W3118173929 cites W3046117953 @default.
- W3118173929 cites W3050926904 @default.
- W3118173929 cites W4251651980 @default.
- W3118173929 doi "https://doi.org/10.1021/acs.inorgchem.0c03309" @default.
- W3118173929 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33356190" @default.
- W3118173929 hasPublicationYear "2020" @default.
- W3118173929 type Work @default.
- W3118173929 sameAs 3118173929 @default.
- W3118173929 citedByCount "22" @default.
- W3118173929 countsByYear W31181739292021 @default.
- W3118173929 countsByYear W31181739292022 @default.
- W3118173929 countsByYear W31181739292023 @default.
- W3118173929 crossrefType "journal-article" @default.
- W3118173929 hasAuthorship W3118173929A5004634467 @default.
- W3118173929 hasAuthorship W3118173929A5004692450 @default.
- W3118173929 hasAuthorship W3118173929A5004810605 @default.
- W3118173929 hasAuthorship W3118173929A5010889732 @default.
- W3118173929 hasAuthorship W3118173929A5029138822 @default.
- W3118173929 hasAuthorship W3118173929A5068209475 @default.
- W3118173929 hasAuthorship W3118173929A5073415848 @default.
- W3118173929 hasAuthorship W3118173929A5081595730 @default.
- W3118173929 hasConcept C120665830 @default.
- W3118173929 hasConcept C121332964 @default.
- W3118173929 hasConcept C133386390 @default.
- W3118173929 hasConcept C149288129 @default.
- W3118173929 hasConcept C181966813 @default.
- W3118173929 hasConcept C185592680 @default.
- W3118173929 hasConcept C192562407 @default.
- W3118173929 hasConcept C26873012 @default.
- W3118173929 hasConcept C30713254 @default.
- W3118173929 hasConcept C39519442 @default.
- W3118173929 hasConcept C49040817 @default.
- W3118173929 hasConcept C520434653 @default.
- W3118173929 hasConcept C79090758 @default.
- W3118173929 hasConcept C8010536 @default.
- W3118173929 hasConcept C97355855 @default.
- W3118173929 hasConceptScore W3118173929C120665830 @default.
- W3118173929 hasConceptScore W3118173929C121332964 @default.
- W3118173929 hasConceptScore W3118173929C133386390 @default.
- W3118173929 hasConceptScore W3118173929C149288129 @default.
- W3118173929 hasConceptScore W3118173929C181966813 @default.
- W3118173929 hasConceptScore W3118173929C185592680 @default.
- W3118173929 hasConceptScore W3118173929C192562407 @default.
- W3118173929 hasConceptScore W3118173929C26873012 @default.
- W3118173929 hasConceptScore W3118173929C30713254 @default.
- W3118173929 hasConceptScore W3118173929C39519442 @default.
- W3118173929 hasConceptScore W3118173929C49040817 @default.
- W3118173929 hasConceptScore W3118173929C520434653 @default.
- W3118173929 hasConceptScore W3118173929C79090758 @default.