Matches in SemOpenAlex for { <https://semopenalex.org/work/W3118299917> ?p ?o ?g. }
- W3118299917 endingPage "1737" @default.
- W3118299917 startingPage "1726" @default.
- W3118299917 abstract "Linker elongation is an important method to systematically adjust porosity and pore size in isoreticular MOFs. In flexible structures, this approach opens the possibility for the systematic analysis of the building blocks and their contribution to the overall flexible behavior enabling tuning of the framework responsivity toward molecular stimuli. In this work, we report two new compounds isoreticular to the highly flexible pillared layer structure DUT-8(Ni) ([Ni2(2,6-ndc)2(dabco)]n, 2,6-ndc = 2,6-naphthalenedicarboxylate, dabco = 1,4-diazabicylo[2.2.2]octane). Aromatic linker 2,6-ndc was substituted by longer carboxylic linkers, namely, 4,4′-biphenyldicarboxylate (4,4′-bpdc) and 4,4′-stilbenedicarboxylate (4,4′-sdc), while the dabco pillar was retained. The structural response of the new compounds toward the desolvation and adsorption of various fluids was studied using advanced in situ PXRD techniques, demonstrating distinct differences in the flexible behavior of three compounds and disclosing the impact of linker structure on the framework response. Theoretical calculations provide mechanistic insights and an energetic rationale for the pronounced differences in switchability observed. The energetics of linker bending and linker–linker dispersion interactions govern the phase transitions in investigated MOFs." @default.
- W3118299917 created "2021-01-18" @default.
- W3118299917 creator A5011954520 @default.
- W3118299917 creator A5013599992 @default.
- W3118299917 creator A5028082964 @default.
- W3118299917 creator A5030419910 @default.
- W3118299917 creator A5053735230 @default.
- W3118299917 creator A5054331809 @default.
- W3118299917 creator A5065033121 @default.
- W3118299917 creator A5088826252 @default.
- W3118299917 date "2021-01-13" @default.
- W3118299917 modified "2023-10-17" @default.
- W3118299917 title "Linker Expansion and Its Impact on Switchability in Pillared-Layer MOFs" @default.
- W3118299917 cites W1862454224 @default.
- W3118299917 cites W1866161350 @default.
- W3118299917 cites W1919212281 @default.
- W3118299917 cites W1968598487 @default.
- W3118299917 cites W1969360633 @default.
- W3118299917 cites W1971822093 @default.
- W3118299917 cites W1973916869 @default.
- W3118299917 cites W1975942961 @default.
- W3118299917 cites W1978683707 @default.
- W3118299917 cites W1981078764 @default.
- W3118299917 cites W1981368803 @default.
- W3118299917 cites W1982952953 @default.
- W3118299917 cites W1987818568 @default.
- W3118299917 cites W1989060947 @default.
- W3118299917 cites W1998143875 @default.
- W3118299917 cites W2014166972 @default.
- W3118299917 cites W2019156918 @default.
- W3118299917 cites W2019481980 @default.
- W3118299917 cites W2023271753 @default.
- W3118299917 cites W2037103351 @default.
- W3118299917 cites W2038533471 @default.
- W3118299917 cites W2045321100 @default.
- W3118299917 cites W2046517735 @default.
- W3118299917 cites W2049375632 @default.
- W3118299917 cites W2060759465 @default.
- W3118299917 cites W2061090028 @default.
- W3118299917 cites W2066485780 @default.
- W3118299917 cites W2071020704 @default.
- W3118299917 cites W2075669271 @default.
- W3118299917 cites W2083356397 @default.
- W3118299917 cites W2087011593 @default.
- W3118299917 cites W2088732846 @default.
- W3118299917 cites W2088827401 @default.
- W3118299917 cites W2092157292 @default.
- W3118299917 cites W2093946771 @default.
- W3118299917 cites W2118298691 @default.
- W3118299917 cites W2143981217 @default.
- W3118299917 cites W2147949826 @default.
- W3118299917 cites W2148284063 @default.
- W3118299917 cites W2149487039 @default.
- W3118299917 cites W2163440962 @default.
- W3118299917 cites W2210120548 @default.
- W3118299917 cites W2333914781 @default.
- W3118299917 cites W2338416931 @default.
- W3118299917 cites W2339342387 @default.
- W3118299917 cites W2622659622 @default.
- W3118299917 cites W2783983610 @default.
- W3118299917 cites W2788735639 @default.
- W3118299917 cites W2805844430 @default.
- W3118299917 cites W2883291226 @default.
- W3118299917 cites W2900729171 @default.
- W3118299917 cites W2901527049 @default.
- W3118299917 cites W2972045540 @default.
- W3118299917 cites W2976088130 @default.
- W3118299917 cites W2991305508 @default.
- W3118299917 cites W2998884734 @default.
- W3118299917 cites W3026497871 @default.
- W3118299917 cites W3087439747 @default.
- W3118299917 cites W4234071678 @default.
- W3118299917 cites W4247076899 @default.
- W3118299917 cites W4251723943 @default.
- W3118299917 doi "https://doi.org/10.1021/acs.inorgchem.0c03218" @default.
- W3118299917 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33439006" @default.
- W3118299917 hasPublicationYear "2021" @default.
- W3118299917 type Work @default.
- W3118299917 sameAs 3118299917 @default.
- W3118299917 citedByCount "6" @default.
- W3118299917 countsByYear W31182999172021 @default.
- W3118299917 countsByYear W31182999172022 @default.
- W3118299917 countsByYear W31182999172023 @default.
- W3118299917 crossrefType "journal-article" @default.
- W3118299917 hasAuthorship W3118299917A5011954520 @default.
- W3118299917 hasAuthorship W3118299917A5013599992 @default.
- W3118299917 hasAuthorship W3118299917A5028082964 @default.
- W3118299917 hasAuthorship W3118299917A5030419910 @default.
- W3118299917 hasAuthorship W3118299917A5053735230 @default.
- W3118299917 hasAuthorship W3118299917A5054331809 @default.
- W3118299917 hasAuthorship W3118299917A5065033121 @default.
- W3118299917 hasAuthorship W3118299917A5088826252 @default.
- W3118299917 hasConcept C111919701 @default.
- W3118299917 hasConcept C127413603 @default.
- W3118299917 hasConcept C150394285 @default.
- W3118299917 hasConcept C171250308 @default.
- W3118299917 hasConcept C178790620 @default.
- W3118299917 hasConcept C185592680 @default.