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- W3118396952 abstract "Abstract Cephalexin monohydrate (CLM) is a well-known antibiotic applied for prohibiting bacterial growth. Herein, the mode of interaction of CLM with both ionic (cetyltrimethylammonium bromide (CTAB) and sodium dodecyl sulfate (SDS)), and nonionic (triton X-100 (TX-100)) surfactants, was investigated using the conductivity measurement and UV–Visible spectroscopic techniques in H2O and NaCl + H2O media at numerous temperatures ranging from 293.15 to 328.15 K. In the current study, the critical micelle concentration (CMC) of CLM + CTAB and CLM + SDS mixed systems was estimated from a sudden and clear breakpoint of specific conductivity (κ) versus the concentration of surfactant plot. A single CMC was found for both CLM + CTAB and CLM + SDS systems in entirely experimental cases studied. The value of CMC of surfactants undergoes a drop in presence of CLM in an aqueous phase and hence, the drug causes an enhancement of the extent of micellization of surfactants. Also, the CMC values of CLM + CTAB and CLM + SDS mixed systems were found to reduce in NaCl + H2O medium and the CMC values were observed to experience a further reduction with increasing concentration of NaCl salt. A negative standard free energy change (∆Gmo) of micellization discloses that the CLM + ionic surfactant micellization is spontaneous. The different thermodynamic parameters of transfer and the enthalpy-entropy compensation parameters of micelle formation were also measured and demonstrated appropriately. The binding constant (Kb) of the CLM + TX-100 mixture has been evaluated from the Benesi-Hildebrand equation and the values were found to be dependent on CLM concentration and temperature. The ∆Hbo and∆Sbo values of CLM + TX-100 mixture reveal the survival of the electrostatic force of interaction along with the presence of hydrophobic interaction developed between the CLM drug and TX-100 surfactant." @default.
- W3118396952 created "2021-01-18" @default.
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- W3118396952 date "2021-03-01" @default.
- W3118396952 modified "2023-09-24" @default.
- W3118396952 title "Interaction of cephalexin monohydrate with surfactants in aqueous and sodium chloride solution at variable temperatures: Conductivity and spectroscopic measurements" @default.
- W3118396952 cites W1882058356 @default.
- W3118396952 cites W1969693738 @default.
- W3118396952 cites W1971561089 @default.
- W3118396952 cites W1973275206 @default.
- W3118396952 cites W1973316236 @default.
- W3118396952 cites W1974675451 @default.
- W3118396952 cites W1989064467 @default.
- W3118396952 cites W1995995697 @default.
- W3118396952 cites W2006376317 @default.
- W3118396952 cites W2006948333 @default.
- W3118396952 cites W2007048270 @default.
- W3118396952 cites W2011511792 @default.
- W3118396952 cites W2017487232 @default.
- W3118396952 cites W2027413699 @default.
- W3118396952 cites W2031832725 @default.
- W3118396952 cites W2033454953 @default.
- W3118396952 cites W2044732571 @default.
- W3118396952 cites W2053096294 @default.
- W3118396952 cites W2058864302 @default.
- W3118396952 cites W2059560778 @default.
- W3118396952 cites W2067652887 @default.
- W3118396952 cites W2073786769 @default.
- W3118396952 cites W2074398988 @default.
- W3118396952 cites W2085629632 @default.
- W3118396952 cites W2092046139 @default.
- W3118396952 cites W2103052993 @default.
- W3118396952 cites W2117826610 @default.
- W3118396952 cites W2127404132 @default.
- W3118396952 cites W2149715361 @default.
- W3118396952 cites W2151087216 @default.
- W3118396952 cites W2162272877 @default.
- W3118396952 cites W2172933641 @default.
- W3118396952 cites W2302245751 @default.
- W3118396952 cites W2325707763 @default.
- W3118396952 cites W2326223387 @default.
- W3118396952 cites W2489175381 @default.
- W3118396952 cites W2558015296 @default.
- W3118396952 cites W2613179442 @default.
- W3118396952 cites W2725950564 @default.
- W3118396952 cites W2728047217 @default.
- W3118396952 cites W2752776322 @default.
- W3118396952 cites W2770882933 @default.
- W3118396952 cites W2775138078 @default.
- W3118396952 cites W2779648713 @default.
- W3118396952 cites W2792695055 @default.
- W3118396952 cites W2793714046 @default.
- W3118396952 cites W2800953334 @default.
- W3118396952 cites W2809821300 @default.
- W3118396952 cites W2883587392 @default.
- W3118396952 cites W2887526243 @default.
- W3118396952 cites W2889324374 @default.
- W3118396952 cites W2898340704 @default.
- W3118396952 cites W2898642220 @default.
- W3118396952 cites W2905303183 @default.
- W3118396952 cites W2908307133 @default.
- W3118396952 cites W2917564247 @default.
- W3118396952 cites W2922699344 @default.
- W3118396952 cites W2938160577 @default.
- W3118396952 cites W2941729635 @default.
- W3118396952 cites W2959968664 @default.
- W3118396952 cites W2965196315 @default.
- W3118396952 cites W3000524483 @default.
- W3118396952 cites W3005170402 @default.
- W3118396952 cites W3010996435 @default.
- W3118396952 cites W3011051967 @default.
- W3118396952 cites W3016020163 @default.
- W3118396952 cites W3038674394 @default.
- W3118396952 cites W3046011452 @default.
- W3118396952 cites W3048056071 @default.
- W3118396952 cites W3109901611 @default.
- W3118396952 cites W2925391454 @default.
- W3118396952 doi "https://doi.org/10.1016/j.molliq.2021.115337" @default.
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