FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3118435671> ?p ?o ?g. }

• W3118435671 endingPage "92" @default.
• W3118435671 startingPage "81" @default.
• W3118435671 abstract "Abstract The origin of life from inanimate matter is still an open question, and our knowledge is still very limited. In this sense, prebiotic chemistry seeks to study and understand how chemical reactions may have contributed to the origin of life. Minerals are of great relevance to prebiotic chemistry, as they may have preconcentrated precursors of biomolecules or biomolecules from diluted solutions, provided protection for biomolecules against UV radiation and hydrolysis, catalysing their reactions and played the role of a primitive genetic code. Montmorillonite, a prebiotic mineral, was shown to be able to adsorb adenine and later also histidine. In addition, histidine adsorption did not displace adenine from the montmorillonite. Kinetic experiments showed that using a whole period of time (7 days) it was not possible to adjust the data to any mathematical kinetic model. Thus, the data were separated into four different adsorption ranges: range 1 (0–60 min), range 2 (60–4320 min), range 3 (4320–7200 min) and range 4 (7200–10 080 min). Range 1 showed adsorption that was too fast, meaning no variations in the adsorption data, and the data of range 3 did not fit in any model used in this work. Thus, range 2 (60–4320 min) and range 4 (7200–10 080 min) were analysed. The adsorption kinetics of histidine adsorption indicated two reaction steps, a quick step (60–4320 min), following the pseudo-first-order model, followed by a slower step (7200–10 080 min) of the pseudo-second order. With these results, isotherms were constructed with times of 1 h and 7 days. The results of the quick step (1 h) showed a reaction that was not thermodynamically favoured. For this time range, Gibbs energy values obtained ranged between 5 and 10 kJ mol −1 at temperatures of 20, 35 and 50°C, and the adsorption occurred due to the balance shift of increase in histidine concentrations. The isotherms of the slow step (7 days) presented negative values, showing a more favourable reaction with Gibbs energy values ranging between −5 and −11 kJ mol −1 . The mathematical modelling of the data indicates that seawater ions are crucial in the adsorption process. Thus, the study provided essential information for prebiotic chemistry, showing that time and the reaction medium should always be taken into account." @default.
• W3118435671 created "2021-01-18" @default.
• W3118435671 creator A5050907593 @default.
• W3118435671 creator A5069626839 @default.
• W3118435671 creator A5081101325 @default.
• W3118435671 date "2020-12-01" @default.
• W3118435671 modified "2023-09-24" @default.
• W3118435671 title "Histidine adsorption onto modified montmorillonite under prebiotic chemistry conditions: a thermodynamic and kinetic study" @default.
• W3118435671 cites W1966846104 @default.
• W3118435671 cites W1972276720 @default.
• W3118435671 cites W1974570607 @default.
• W3118435671 cites W1975299131 @default.
• W3118435671 cites W1978524762 @default.
• W3118435671 cites W1984953206 @default.
• W3118435671 cites W2000997907 @default.
• W3118435671 cites W2004060108 @default.
• W3118435671 cites W2007601264 @default.
• W3118435671 cites W2010699269 @default.
• W3118435671 cites W2012775989 @default.
• W3118435671 cites W2013920849 @default.
• W3118435671 cites W2014827114 @default.
• W3118435671 cites W2020234724 @default.
• W3118435671 cites W2021246042 @default.
• W3118435671 cites W2024253082 @default.
• W3118435671 cites W2027902774 @default.
• W3118435671 cites W2031656009 @default.
• W3118435671 cites W2032718742 @default.
• W3118435671 cites W2035118220 @default.
• W3118435671 cites W2040807550 @default.
• W3118435671 cites W2041360771 @default.
• W3118435671 cites W2046707970 @default.
• W3118435671 cites W2046711717 @default.
• W3118435671 cites W2053220459 @default.
• W3118435671 cites W2056784239 @default.
• W3118435671 cites W2059087339 @default.
• W3118435671 cites W2061652147 @default.
• W3118435671 cites W2071707338 @default.
• W3118435671 cites W2086143970 @default.
• W3118435671 cites W2088145262 @default.
• W3118435671 cites W2090907620 @default.
• W3118435671 cites W2092063097 @default.
• W3118435671 cites W2093268150 @default.
• W3118435671 cites W2094064361 @default.
• W3118435671 cites W2103249806 @default.
• W3118435671 cites W2106527911 @default.
• W3118435671 cites W2116262448 @default.
• W3118435671 cites W2132086507 @default.
• W3118435671 cites W2136738016 @default.
• W3118435671 cites W2149788035 @default.
• W3118435671 cites W2168262102 @default.
• W3118435671 cites W2179731808 @default.
• W3118435671 cites W2210695211 @default.
• W3118435671 cites W2252298600 @default.
• W3118435671 cites W2269591580 @default.
• W3118435671 cites W2276611055 @default.
• W3118435671 cites W2300903171 @default.
• W3118435671 cites W2329977490 @default.
• W3118435671 cites W2506711127 @default.
• W3118435671 cites W2734349048 @default.
• W3118435671 cites W2777646647 @default.
• W3118435671 cites W2793699952 @default.
• W3118435671 cites W2900144376 @default.
• W3118435671 cites W3014310515 @default.
• W3118435671 cites W3028884230 @default.
• W3118435671 cites W3211985345 @default.
• W3118435671 cites W4857921 @default.
• W3118435671 doi "https://doi.org/10.1017/s1473550420000373" @default.
• W3118435671 hasPublicationYear "2020" @default.
• W3118435671 type Work @default.
• W3118435671 sameAs 3118435671 @default.
• W3118435671 citedByCount "1" @default.
• W3118435671 countsByYear W31184356712022 @default.
• W3118435671 crossrefType "journal-article" @default.
• W3118435671 hasAuthorship W3118435671A5050907593 @default.
• W3118435671 hasAuthorship W3118435671A5069626839 @default.
• W3118435671 hasAuthorship W3118435671A5081101325 @default.
• W3118435671 hasConcept C121332964 @default.
• W3118435671 hasConcept C127413603 @default.
• W3118435671 hasConcept C1276947 @default.
• W3118435671 hasConcept C148898269 @default.
• W3118435671 hasConcept C150394285 @default.
• W3118435671 hasConcept C150846664 @default.
• W3118435671 hasConcept C178790620 @default.
• W3118435671 hasConcept C181199279 @default.
• W3118435671 hasConcept C185592680 @default.
• W3118435671 hasConcept C190161988 @default.
• W3118435671 hasConcept C2775980262 @default.
• W3118435671 hasConcept C2777515222 @default.
• W3118435671 hasConcept C2778460671 @default.
• W3118435671 hasConcept C2994569158 @default.
• W3118435671 hasConcept C42360764 @default.
• W3118435671 hasConcept C49853544 @default.
• W3118435671 hasConcept C55493867 @default.
• W3118435671 hasConcept C62520636 @default.
• W3118435671 hasConcept C87355193 @default.
• W3118435671 hasConcept C94412978 @default.
• W3118435671 hasConceptScore W3118435671C121332964 @default.
• W3118435671 hasConceptScore W3118435671C127413603 @default.

• next