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- W3118450188 endingPage "151" @default.
- W3118450188 startingPage "121" @default.
- W3118450188 abstract "Halonium ions act as particularly strong halogen bond donors by simultaneously accepting electrons into both lobes of their empty p-orbital, yielding three-center halogen bonds. These bonds possess charge-transfer and electrostatic characters and are exceptionally strong. Their fundamental studies give unique insights not only into halogen bonding but also for the understanding of chemical bonding in general. Three-center halogen bonds have an increasing scope of applications in various fields of chemistry. As the three-center halogen bond modulates the reactivity of the halonium ions, it is a valuable tool for synthetic organic chemistry. It has distinctly different properties as compared with the coordination bonds of transition metals and to analogous hydrogen bonds and is hence applicable as a complementary tool, for example, in crystal engineering and in supramolecular chemistry. A general overview of the three-center halogen bond and its current applications is presented herein." @default.
- W3118450188 created "2021-01-18" @default.
- W3118450188 creator A5018969156 @default.
- W3118450188 creator A5028527361 @default.
- W3118450188 date "2021-01-09" @default.
- W3118450188 modified "2023-09-23" @default.
- W3118450188 title "The Three‐Center Halogen Bond" @default.
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