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- W3118465265 abstract "Ir-catalyzed asymmetric tandem allylation/iso-Pictet–Spengler cyclization of arylidenaminomalonates with indolyl allylic methyl carbonates was successfully developed, which provided a direct and practical approach to access synthetically useful and biologically active tetrahydro-γ-carboline derivatives bearing multiple functional groups and stereogenic centers in good to high yields and excellent stereoselective control (44%–96% yields, >20:1 dr, 94% → 99% ee). A wide range of substrate generality, easily available substrates, and simple chiral catalytic system displayed great potential practicality of this efficient protocol." @default.
- W3118465265 created "2021-01-18" @default.
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- W3118465265 date "2021-01-11" @default.
- W3118465265 modified "2023-10-14" @default.
- W3118465265 title "Ir-Catalyzed Asymmetric Tandem Allylation/<i>Iso</i>-Pictet–Spengler Cyclization Reaction for the Enantioselective Construction of Tetrahydro-γ-carbolines" @default.
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- W3118465265 doi "https://doi.org/10.1021/acs.orglett.0c03909" @default.
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