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• W3118562094 startingPage "974" @default.
• W3118562094 abstract "A palladium-catalyzed three-component carbonylative reaction for the synthesis of 3H-1,2,4-triazol-3-ones from hydrazonoyl chlorides and NaN3 has been achieved. The reaction presumably proceeds through a cascade carbonylation, acyl azide formation, Curtius rearrangement, and intramolecular nucleophilic addition sequence. A wide variety of structurally diverse 3H-1,2,4-triazol-3-ones were constructed in moderate to excellent yields. Benzene-1,3,5-triyl triformate (TFBen) was applied as a solid and convenient CO surrogate." @default.
• W3118562094 created "2021-01-18" @default.
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• W3118562094 date "2021-01-12" @default.
• W3118562094 modified "2023-10-18" @default.
• W3118562094 title "Palladium-Catalyzed Cascade Carbonylative Synthesis of 1,2,4-Triazol-3-ones from Hydrazonoyl Chlorides and NaN₃" @default.
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• W3118562094 doi "https://doi.org/10.1021/acs.orglett.0c04167" @default.
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